Fe(S₂C₂(SCH₃)2)(CO)2(P(C₆H₅)3)

Base Information

• Chemical Name: Fe(S₂C₂(SCH₃)2)(CO)2(P(C₆H₅)3)
• CAS No.: 97390-96-0
• Molecular Formula: C₂₄H₂₁FeO₂PS₄
• Molecular Weight: 556.514
• Mol file: 97390-96-0.mol

Synonyms:Fe(S₂C₂(SCH₃)2)(CO)2(P(C₆H₅)3)

Chemical Property of Fe(S₂C₂(SCH₃)2)(CO)2(P(C₆H₅)3)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of Fe(S₂C₂(SCH₃)2)(CO)2(P(C₆H₅)3)

There total 6 articles about Fe(S₂C₂(SCH₃)2)(CO)2(P(C₆H₅)3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

(iron)2(S2C2(Smethyl)2)(carbonyl)4((phenyl)3phosphine)2 (97390-97-1) → Fe(S2C2(SCH3)2)(CO)2(P(C6H5)3) (97390-96-0)

Guidance literature:

With air; H⁽¹⁺⁾; In not given; exposure soln. of educt to air in presence of acid;

Reference yield: 40.0%

iron(η2-CS2(methyl))(carbonyl)2((phenyl)3phosphine)2{PF6} (71004-19-8) → Fe(S2C2(SCH3)2)(CO)2(P(C6H5)3) (97390-96-0)

Guidance literature:

With sodium amalgame; In tetrahydrofuran; educt in THF added to 1% sodium amalgam, reacted for 1.5 h at room temp.; isolated by crystn. from pentane;

Reference yield: 40.0%

iron(η2-CS2(methyl))(carbonyl)2((phenyl)3phosphine)iodide (72598-18-6) → iron((methyl)2tetrathiooxalate)(carbonyl)2((phenyl)3phosphine) (97390-96-0)

Guidance literature:

With Na#Hg; In tetrahydrofuran; Under N2, addn. of Fe(η2-CS2CH3)(CO)2(PPh3)2(I) in THF to sodium amalgam. Soln. turns purple, then blue. Stirring for 1.5 h at room temp.; Monitored by TLC, silica gel chromy. (pentane).;

DOI:10.1021/om00091a013

upstream raw materials:

(iron)2(S₂C₂(Smethyl)2)(carbonyl)4((phenyl)3phosphine)2

iron(η2-CS2(methyl))(carbonyl)2((phenyl)3phosphine)2{PF6}

iron(η2-CS2(methyl))(carbonyl)2((phenyl)3phosphine)iodide