iron(η2-CS2(methyl))(carbonyl)2((phenyl)3phosphine)2{PF6}

Base Information

• Chemical Name: iron(η2-CS2(methyl))(carbonyl)2((phenyl)3phosphine)2{PF6}
• CAS No.: 71004-19-8
• Molecular Formula: C₄₀H₃₃FeO₂P₂S₂*F₆P
• Molecular Weight: 872.592
• Mol file: 71004-19-8.mol

Synonyms:iron(η2-CS2(methyl))(carbonyl)2((phenyl)3phosphine)2{PF6}

Chemical Property of iron(η2-CS2(methyl))(carbonyl)2((phenyl)3phosphine)2{PF6}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of iron(η2-CS2(methyl))(carbonyl)2((phenyl)3phosphine)2{PF6}

There total 1 articles about iron(η2-CS2(methyl))(carbonyl)2((phenyl)3phosphine)2{PF6} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

sodium hexaflorophosphate + [Fe(CO)2(PPh3)2(η2-CS2)] (64424-68-6) → (Fe(η2-CS2Me)(CO)2(PPh3)2)PF6 (71004-19-8)

Guidance literature:

With methyl iodide; In dichloromethane; water; under N2 atm. saturated soln. NaPF6 in water added to mixt. Fe(CS2)(CO)2(PPh3)2 and MeI in dichloromethane and stirred at room temp. for 2-3 h; organic layer washed with water and dried over Na2SO4, product crystd. from dichloromethane/hexane; elem. anal.;

Reference yield: 40.0%

iron(η2-CS2(methyl))(carbonyl)2((phenyl)3phosphine)2{PF6} (71004-19-8) → Fe(S2C2(SCH3)2)(CO)2(P(C6H5)3) (97390-96-0)

Guidance literature:

With sodium amalgame; In tetrahydrofuran; educt in THF added to 1% sodium amalgam, reacted for 1.5 h at room temp.; isolated by crystn. from pentane;

Reference yield: 40.0%

iron(η2-CS2(methyl))(carbonyl)2((phenyl)3phosphine)2{PF6} (71004-19-8) → iron((methyl)2tetrathiooxalate)(carbonyl)2((phenyl)3phosphine) (97390-96-0)

Guidance literature:

With Na#Hg; In tetrahydrofuran; Under N2, addn. of Fe(η2-CS2CH3)(CO)2(PPh3)2(PF6) in THF to sodium amalgam. Soln. turns purple, then blue. Stirring for 1.5 h at room temp.; Monitored by TLC, silica gel chromy. (pentane).;

DOI:10.1021/om00091a013

upstream raw materials:

[Fe(CO)2(PPh3)2(η2-CS2)]

Downstream raw materials:

iron((methyl)2tetrathiooxalate)(carbonyl)2((phenyl)3phosphine)

(iron)2(S₂C₂(Smethyl)2)(carbonyl)4((phenyl)3phosphine)2

Fe(S₂C₂(SCH₃)2)(CO)2(P(C₆H₅)3)

Fe(CS)(CO)2((C₆H₅)2PCH₂CH₂P(C₆H₅)2)

Refernces