trimethyl(phenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methyl)silane

Base Information

• Chemical Name: trimethyl(phenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methyl)silane
• CAS No.: 83947-57-3
• Molecular Formula: C₁₆H₂₇BO₂Si
• Molecular Weight: 290.286
• Mol file: 83947-57-3.mol

Synonyms:trimethyl(phenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methyl)silane

Chemical Property of trimethyl(phenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methyl)silane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of trimethyl(phenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methyl)silane

There total 6 articles about trimethyl(phenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methyl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

2,3-dimethyl-2,3-butane diol (76-09-5) + diazomethyl-trimethyl-silane (18107-18-1) + phenylboronic acid (98-80-6) → trimethyl(phenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methyl)silane (83947-57-3)

Guidance literature:

diazomethyl-trimethyl-silane; phenylboronic acid; In toluene; at 100 ℃; for 4h; Inert atmosphere; Schlenk technique;

2,3-dimethyl-2,3-butane diol; With water; In toluene; at 100 ℃; for 16h; Solvent; Temperature; Inert atmosphere; Schlenk technique;

DOI:10.1039/c9ob01006h

Reference yield: 67.0%

benzyltrimethylsilane (770-09-2) + bis(pinacol)diborane (73183-34-3) → trimethyl(phenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methyl)silane (83947-57-3)

Guidance literature:

With cobalt(II) bis(trimethylsilyl)amide; In hexane; at 80 ℃; for 96h; Glovebox; Inert atmosphere;

DOI:10.1002/anie.202110821

Reference yield: 67.0%

triphenylboroxine (3262-89-3) + 2,3-dimethyl-2,3-butane diol (76-09-5) + diazomethyl-trimethyl-silane (18107-18-1) → trimethyl(phenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methyl)silane (83947-57-3)

Guidance literature:

triphenylboroxine; diazomethyl-trimethyl-silane; With N-ethyl-N,N-diisopropylamine; In hexane; toluene; at 85 ℃; for 1h; Inert atmosphere;

2,3-dimethyl-2,3-butane diol; In hexane; toluene; at 20 ℃; Inert atmosphere;

DOI:10.1039/c7sc02264f

upstream raw materials:

ethylene glycol phenyl(trimethylsilyl)methaneboronate

2,3-dimethyl-2,3-butanediol monohydrate

triphenylboroxine

2,3-dimethyl-2,3-butane diol

Downstream raw materials:

Diphenylmethane

1,3,3-triphenylpropan-1-one

4,4-diphenyl-1-butene

benzhydryl methyl ether