N-[(4-chlorophenyl)(methyl)(oxo)-λ⁶-sulfanylidene]cyanamide

Base Information

• Chemical Name: N-[(4-chlorophenyl)(methyl)(oxo)-λ⁶-sulfanylidene]cyanamide
• CAS No.: 1620028-46-7
• Molecular Formula: C₈H₇ClN₂OS
• Molecular Weight: 214.675
• Mol file: 1620028-46-7.mol

Synonyms:N-[(4-chlorophenyl)(methyl)(oxo)-λ⁶-sulfanylidene]cyanamide

Chemical Property of N-[(4-chlorophenyl)(methyl)(oxo)-λ⁶-sulfanylidene]cyanamide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-[(4-chlorophenyl)(methyl)(oxo)-λ⁶-sulfanylidene]cyanamide

There total 7 articles about N-[(4-chlorophenyl)(methyl)(oxo)-λ⁶-sulfanylidene]cyanamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

CYANAMID (420-04-2) + methyl 4-chlorophenyl sulfoxide (934-73-6) → N-[(4-chlorophenyl)(methyl)(oxo)-λ6-sulfanylidene]cyanamide (1620028-46-7)

Guidance literature:

CYANAMID; methyl 4-chlorophenyl sulfoxide; With potassium tert-butylate; In water; for 0.166667h; Sealed tube;

With N-chloro-succinimide; In water; at 20 ℃; for 2h; Sealed tube;

DOI:10.1039/c6ob02691e

Reference yield: 69.0%

(4-chlorophenyl)(imino)(methyl)-λ6-sulfanone (22132-99-6) + copper(l) cyanide → N-[(4-chlorophenyl)(methyl)(oxo)-λ6-sulfanylidene]cyanamide (1620028-46-7)

Guidance literature:

With N,N,N,N,-tetramethylethylenediamine; oxygen; sodium sulfate; copper(ll) bromide; In acetonitrile; at 50 ℃; for 12h; Schlenk technique; Sealed tube;

DOI:10.1039/c4cc03439b

Reference yield: 51.0%

(4-chlorophenyl)(imino)(methyl)-λ6-sulfanone (22132-99-6) + acetonitrile (75-05-8,26809-02-9) → N-[(4-chlorophenyl)(methyl)(oxo)-λ6-sulfanylidene]cyanamide (1620028-46-7)

Guidance literature:

With copper(I) oxide; di-tert-butyl peroxide; oxygen; at 120 ℃; for 24h; Schlenk technique; Sealed tube;

DOI:10.1016/j.tetlet.2015.11.025

upstream raw materials:

(4-chlorophenyl)(imino)(methyl)-λ⁶-sulfanone

2,2'-azobis(isobutyronitrile)

acetonitrile

1-Chloro-4-iodobenzene