N-allyl-4-methyl-N-(3-methylbut-2-en-1-yl)benzenesulfonamide

Base Information

• Chemical Name: N-allyl-4-methyl-N-(3-methylbut-2-en-1-yl)benzenesulfonamide
• CAS No.: 135979-17-8
• Molecular Formula: C₁₅H₂₁NO₂S
• Molecular Weight: 279.403
• Mol file: 135979-17-8.mol

Synonyms:N-allyl-4-methyl-N-(3-methylbut-2-en-1-yl)benzenesulfonamide

Chemical Property of N-allyl-4-methyl-N-(3-methylbut-2-en-1-yl)benzenesulfonamide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-allyl-4-methyl-N-(3-methylbut-2-en-1-yl)benzenesulfonamide

There total 10 articles about N-allyl-4-methyl-N-(3-methylbut-2-en-1-yl)benzenesulfonamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

4-methyl-N-(2-propenyl)benzenesulfonamide (50487-71-3) + prenyl bromide (870-63-3) → N-allyl-4-methyl-N-(3-methylbut-2-en-1-yl)benzenesulfonamide (135979-17-8)

Guidance literature:

With potassium carbonate; In acetonitrile; for 5h; Reflux;

DOI:10.1021/ja1068036

Reference yield:

4-methyl-N-(3-methylbut-2-enyl)benzenesulfonamide (78388-19-9) + allyl bromide (106-95-6) → N-allyl-4-methyl-N-(3-methylbut-2-en-1-yl)benzenesulfonamide (135979-17-8)

Guidance literature:

With caesium carbonate; In 1,4-dioxane; at 20 ℃;

DOI:10.1055/s-0034-1379428

Reference yield:

4-methyl-N-(3-methylbut-2-enyl)benzenesulfonamide (78388-19-9) → N-allyl-4-methyl-N-(3-methylbut-2-en-1-yl)benzenesulfonamide (135979-17-8)

Guidance literature:

4-methyl-N-(3-methylbut-2-enyl)benzenesulfonamide; With caesium carbonate; In N,N-dimethyl-formamide; for 0.166667h;

allyl halide; In N,N-dimethyl-formamide; at 20 ℃;

DOI:10.1055/s-0034-1379428

upstream raw materials:

4-methyl-N-(2-propenyl)benzenesulfonamide

prenyl bromide

4-methyl-N-(3-methylbut-2-enyl)benzenesulfonamide

p-toluenesulfonyl chloride

Downstream raw materials:

N-p-toluenesulfonyl-3-(1,1-dimethyl-3-ethoxycarbonyl-3-buten-1-yl)-4-p-toluenesulfonylmethyl-pyrrolidine

N-p-toluenesulfonyl-3-(1,1-dimethyl-3-ethoxycarbonyl-3-buten-1-yl)-4-p-toluenesulfonylmethyl-pyrrolidine

1-[(4-methylphenyl)sulfonyl]-2,5-dihydro-1H-pyrrole

ethyl 3-[4-(1-azido-1-methylethyl)-1-((4-methylbenzene)sulfonyl)pyrrolidin-3-yl]propanoate