Benzoic acid (4R,5S)-5-hydroxymethyl-2,2,5-trimethyl-[1,3]dioxolan-4-ylmethyl ester

Base Information

Chemical Name:Benzoic acid (4R,5S)-5-hydroxymethyl-2,2,5-trimethyl-[1,3]dioxolan-4-ylmethyl ester
CAS No.:119927-30-9
Molecular Formula:C₁₅H₂₀O₅
Molecular Weight:280.321
Hs Code.:

Synonyms:Benzoic acid (4R,5S)-5-hydroxymethyl-2,2,5-trimethyl-[1,3]dioxolan-4-ylmethyl ester

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Benzoic acid (4R,5S)-5-hydroxymethyl-2,2,5-trimethyl-[1,3]dioxolan-4-ylmethyl ester

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Technology Process of Benzoic acid (4R,5S)-5-hydroxymethyl-2,2,5-trimethyl-[1,3]dioxolan-4-ylmethyl ester

There total 4 articles about Benzoic acid (4R,5S)-5-hydroxymethyl-2,2,5-trimethyl-[1,3]dioxolan-4-ylmethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 95237-52-8
4-O-benzoyl-2-C-methyl-D-erythritol

: 77-76-9
2,2-dimethoxy-propane

: 95237-53-9
4-O-benzoyl-1,2-O-isopropylidene-2-C-methyl-D-erythritol

: 119927-30-9
Benzoic acid (4R,5S)-5-hydroxymethyl-2,2,5-trimethyl-[1,3]dioxolan-4-ylmethyl ester

: 119927-29-6
4-O-benzoyl-1,3-O-isopropylidene-2-C-methyl-D-erythritol

Guidance literature:: With pyridinium p-toluenesulfonate; In acetone; at -30 ℃; for 5h;
DOI:10.1016/0008-6215(88)84046-1

Reference yield:

: 81841-75-0
4-O-benzoyl-2-O-benzyl-2-C-methyl-D-erythritol

: 119927-30-9
Benzoic acid (4R,5S)-5-hydroxymethyl-2,2,5-trimethyl-[1,3]dioxolan-4-ylmethyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 96 percent / hydrogen, acetic acid / 10 percent palladium-on-charcoal / ethanol / 24 h / Ambient temperature

2: 38 percent / p-toluenesulfonic acid / dimethylformamide / 10 h / 0 °C

With hydrogen; toluene-4-sulfonic acid; acetic acid; palladium on activated charcoal; In ethanol; N,N-dimethyl-formamide;
DOI:10.1016/0008-6215(88)84046-1

Reference yield:

: 5-O-benzoyl-3-O-benzyl-3-C-methyl-D-ribofuranose

: 119927-30-9
Benzoic acid (4R,5S)-5-hydroxymethyl-2,2,5-trimethyl-[1,3]dioxolan-4-ylmethyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 76 percent / periodate

2: 96 percent / hydrogen, acetic acid / 10 percent palladium-on-charcoal / ethanol / 24 h / Ambient temperature

3: 38 percent / p-toluenesulfonic acid / dimethylformamide / 10 h / 0 °C

With periodate; hydrogen; toluene-4-sulfonic acid; acetic acid; palladium on activated charcoal; In ethanol; N,N-dimethyl-formamide;
DOI:10.1016/0008-6215(88)84046-1