(2,6-(CHMe₂)2C₆H₃NC(CH₃)CHC(CH₃)NC₆H₃-2,6-(CHMe₂)2)VC(t)Bu(OTf)

Base Information

• Chemical Name: (2,6-(CHMe₂)2C₆H₃NC(CH₃)CHC(CH₃)NC₆H₃-2,6-(CHMe₂)2)VC(t)Bu(OTf)
• CAS No.: 765916-14-1
• Molecular Formula: C₃₅H₅₀F₃N₂O₃SV
• Molecular Weight: 686.796
• Mol file: 765916-14-1.mol

Synonyms:(2,6-(CHMe₂)2C₆H₃NC(CH₃)CHC(CH₃)NC₆H₃-2,6-(CHMe₂)2)VC(t)Bu(OTf)

Chemical Property of (2,6-(CHMe₂)2C₆H₃NC(CH₃)CHC(CH₃)NC₆H₃-2,6-(CHMe₂)2)VC(t)Bu(OTf)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (2,6-(CHMe₂)2C₆H₃NC(CH₃)CHC(CH₃)NC₆H₃-2,6-(CHMe₂)2)VC(t)Bu(OTf)

There total 1 articles about (2,6-(CHMe₂)2C₆H₃NC(CH₃)CHC(CH₃)NC₆H₃-2,6-(CHMe₂)2)VC(t)Bu(OTf) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

(2,6-(CHMe2)2C6H3NC(CH3)CHC(CH3)NC6H3-2,6-(CHMe2)2)V=CH(t)Bu(CH2SiMe3) + silver trifluoromethanesulfonate (2923-28-6) → (2,6-(CHMe2)2C6H3NC(CH3)CHC(CH3)NC6H3-2,6-(CHMe2)2)VC(t)Bu(OTf) (765916-14-1)

Guidance literature:

In not given;

DOI:10.1021/ja0472376

Reference yield: 91.0%

(2,6-(CHMe2)2C6H3NC(CH3)CHC(CH3)NC6H3-2,6-(CHMe2)2)VC(t)Bu(OTf) (765916-14-1) + sodium 2-phosphaethynolate (174322-77-1) → C35H50N2OPV

Guidance literature:

In tetrahydrofuran; at -35 ℃; for 1h; Inert atmosphere;

DOI:10.1002/anie.202107475

Reference yield: 58.0%

diethyl ether (60-29-7,927820-24-4) + (2,6-(CHMe2)2C6H3NC(CH3)CHC(CH3)NC6H3-2,6-(CHMe2)2)VC(t)Bu(OTf) (765916-14-1) → (((CH3)2CH)2C6H3NC(CH2)CHC(CH3)NC6H3(CH(CH3)2)2)V(CC(CH3)3)(O(C2H5)2) (1172127-17-1)

Guidance literature:

With tert.-butyl lithium; In pentane; byproducts: H-t-Bu, LiSO3CF3; under N2 or Ar; V complex dissolved pentane; cooled to -35°C; added to cold (-35°C) pentane soln. of t-BuLi; stirred for 5 min; 4 drops of Et2O added; stirred for 1 h; dried under vac.; extd. with hexane; filtered; filtrate reduced in vol. in vac.; crystd. at -35°C;

DOI:10.1021/om900115v

upstream raw materials:

silver trifluoromethanesulfonate

Downstream raw materials:

[([2,6-i-Pr₂C₆H₃NC(Me)]2CH)V(neopentylidyne)(THF)][B(C₆F₅)4]

(((CH₃)2CH)2C₆H₃NC(CH₂)CHC(CH₃)NC₆H₃(CH(CH₃)2)2)V(CC(CH₃)3)(OC₄H₈)

(((CH₃)2CH)2C₆H₃NC(CH₂)CHC(CH₃)NC₆H₃(CH(CH₃)2)2)V(CC(CH₃)3)(O(C₂H₅)2)