η-benzhydrol-η-cyclopentadienyliron(II) hexafluorophosphate

Base Information

• Chemical Name: η-benzhydrol-η-cyclopentadienyliron(II) hexafluorophosphate
• CAS No.: 86731-50-2
• Molecular Formula: C₁₈H₁₇FeO*F₆P
• Molecular Weight: 450.144
• Mol file: 86731-50-2.mol

Synonyms:η-benzhydrol-η-cyclopentadienyliron(II) hexafluorophosphate

Chemical Property of η-benzhydrol-η-cyclopentadienyliron(II) hexafluorophosphate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of η-benzhydrol-η-cyclopentadienyliron(II) hexafluorophosphate

There total 3 articles about η-benzhydrol-η-cyclopentadienyliron(II) hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

(η(5)-cyclopentadienyl)[(1,2,2,3,3,4-η(6))-benzophenone]iron(II) hexafluorophosphate → η-benzhydrol-η-cyclopentadienyliron(II) hexafluorophosphate (86731-50-2)

Guidance literature:

With sulfuric acid; In sulfuric acid; acetone; Electrochem. Process; (N2); <(C5H5)Fe(C13H10O)>PF6 is electrolysed in a 1/1 mixt. of 1 N H2SO4 and acetone at 0°C in the dark at a Hg electrode, potential of working electrode: -0.9 V SCE, after electrolysis addn. of 60 % aq. HPF6; evapn. (vac.), extn. (CH2Cl2, 0°C, in the dark), drying (MgSO4),concg., pptd. with ether, filtration, washing (ether);

DOI:10.1016/S0022-328X(00)99554-8

Reference yield: 58.0%

ammonium hexafluorophosphate + ferrocene (102-54-5,55404-68-7) + 1,1-Diphenylmethanol (91-01-0) → η-benzhydrol-η-cyclopentadienyliron(II) hexafluorophosphate (86731-50-2)

Guidance literature:

With aluminium trichloride; aluminium; In water; other Radiation; 0.02 mol metal addn. to arene, Fe- and Al-salts mixt. in 1,2,4-C6H3Cl3 (ratio arene:Fe:AlCl3:Al=1:3:6:11), homogenization (stirring), mixt. irradiation in microwave oven (850 W) for 4 min, ice addn. (AlCl3 decompn.),filtration, filtrate washing (Et2O); filtration, treating with aq. NH4-salt, ppt. filtration off through sinter, washing (i-PrOH, Et2O);

DOI:10.1039/P19950000743

Reference yield: 19.0%

ammonium hexafluorophosphate + ferrocene (102-54-5,55404-68-7) + benzophenone (119-61-9) → η-benzhydrol-η-cyclopentadienyliron(II) hexafluorophosphate (86731-50-2)

Guidance literature:

With aluminium trichloride; aluminium; In water; other Radiation; 0.02 mol metal addn. to arene, Fe- and Al-salts mixt. in 1,2,4-C6H3Cl3 (ratio arene:Fe:AlCl3:Al=1:2:4:5.5), homogenization (stirring), mixt. irradiation in microwave oven (850 W) for 5 min, ice addn. (AlCl3 decompn.), filtration, filtrate washing (Et2O); filtration, treating with aq. NH4-salt, ppt. filtration off through sinter, washing (i-PrOH, Et2O);

DOI:10.1039/P19950000743

upstream raw materials:

ferrocene

1,1-Diphenylmethanol

benzophenone

Refernces

• 1、 Rudulier, M. Le,Moinet, C.,Raoult, E.. "PREPARATION DE CATIONS 5-CYCLOPENTADIENYL FER η6-ARENE>+ COMPORTANT UNE FONCTION OXIME, CETONE, AMINE OU ALCOOL EN α DU LIGANDE ARENE". . p. 209 - 224. Retrieved 2007/10/02.