2α-(acetoxymethyl)-2β-methyl-3α-methoxy-3β-<((p-nitrobenzoyl)oxy)methyl>-6β-(phenoxyacetamido)penam (R)-sulfoxide

Base Information

Chemical Name:2α-(acetoxymethyl)-2β-methyl-3α-methoxy-3β-<((p-nitrobenzoyl)oxy)methyl>-6β-(phenoxyacetamido)penam (R)-sulfoxide
CAS No.:99809-83-3
Molecular Formula:C₂₆H₂₇N₃O₁₁S
Molecular Weight:589.58
Hs Code.:

Synonyms:2α-(acetoxymethyl)-2β-methyl-3α-methoxy-3β-<((p-nitrobenzoyl)oxy)methyl>-6β-(phenoxyacetamido)penam (R)-sulfoxide

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Chemical Property of 2α-(acetoxymethyl)-2β-methyl-3α-methoxy-3β-<((p-nitrobenzoyl)oxy)methyl>-6β-(phenoxyacetamido)penam (R)-sulfoxide

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Technology Process of 2α-(acetoxymethyl)-2β-methyl-3α-methoxy-3β-<((p-nitrobenzoyl)oxy)methyl>-6β-(phenoxyacetamido)penam (R)-sulfoxide

There total 4 articles about 2α-(acetoxymethyl)-2β-methyl-3α-methoxy-3β-<((p-nitrobenzoyl)oxy)methyl>-6β-(phenoxyacetamido)penam (R)-sulfoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

: 99809-79-7
2α-(acetoxymethyl)-2β-methyl-3α-methoxy-3β-<((p-nitrobenzoyl)oxy)methyl>-6β-(phenoxyacetamido)penam

: 99809-82-2
2α-(acetoxymethyl)-2β-methyl-3α-methoxy-3β-<((p-nitrobenzoyl)oxy)methyl>-6β-(phenoxyacetamido)penam (S)-sulfoxide

: 99809-83-3
2α-(acetoxymethyl)-2β-methyl-3α-methoxy-3β-<((p-nitrobenzoyl)oxy)methyl>-6β-(phenoxyacetamido)penam (R)-sulfoxide

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 0 ℃; for 1h;
DOI:10.1021/jo00354a028

Reference yield:

: 122-04-3
4-nitro-benzoyl chloride

: 99809-83-3
2α-(acetoxymethyl)-2β-methyl-3α-methoxy-3β-<((p-nitrobenzoyl)oxy)methyl>-6β-(phenoxyacetamido)penam (R)-sulfoxide

Guidance literature:: Multi-step reaction with 3 steps

1: 87 percent / pyridine / 1 h / Ambient temperature

2: 70 percent / silver acetate / 0.33 h / 100 °C

3: 55 percent / 91percent m-chloroperoxybenzoic acid / CH₂Cl₂ / 1 h / 0 °C

With pyridine; silver(I) acetate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane;
DOI:10.1021/jo00354a028

Reference yield:

: 99881-82-0
3α-bromo-3β-methyl-4β-(hydroxymethyl)-4α-methoxy-7β-(phenoxyacetamido)cepham

: 99809-83-3
2α-(acetoxymethyl)-2β-methyl-3α-methoxy-3β-<((p-nitrobenzoyl)oxy)methyl>-6β-(phenoxyacetamido)penam (R)-sulfoxide

Guidance literature:: Multi-step reaction with 3 steps

1: 87 percent / pyridine / 1 h / Ambient temperature

2: 70 percent / silver acetate / 0.33 h / 100 °C

3: 55 percent / 91percent m-chloroperoxybenzoic acid / CH₂Cl₂ / 1 h / 0 °C

With pyridine; silver(I) acetate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane;
DOI:10.1021/jo00354a028