O-(2-azido-3,4,6-tri-O-benzyl-2-deoxy-α-D-glucopyranosyl)-(1->6)-1-O-allyl-3,4,6-tri-O-benzyl-D-myo-inositol

Base Information

Chemical Name:O-(2-azido-3,4,6-tri-O-benzyl-2-deoxy-α-D-glucopyranosyl)-(1->6)-1-O-allyl-3,4,6-tri-O-benzyl-D-myo-inositol
CAS No.:760987-55-1
Molecular Formula:C₅₇H₆₁N₃O₁₀
Molecular Weight:948.125
Hs Code.:

Synonyms:O-(2-azido-3,4,6-tri-O-benzyl-2-deoxy-α-D-glucopyranosyl)-(1->6)-1-O-allyl-3,4,6-tri-O-benzyl-D-myo-inositol

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Chemical Property of O-(2-azido-3,4,6-tri-O-benzyl-2-deoxy-α-D-glucopyranosyl)-(1->6)-1-O-allyl-3,4,6-tri-O-benzyl-D-myo-inositol

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Technology Process of O-(2-azido-3,4,6-tri-O-benzyl-2-deoxy-α-D-glucopyranosyl)-(1->6)-1-O-allyl-3,4,6-tri-O-benzyl-D-myo-inositol

There total 8 articles about O-(2-azido-3,4,6-tri-O-benzyl-2-deoxy-α-D-glucopyranosyl)-(1->6)-1-O-allyl-3,4,6-tri-O-benzyl-D-myo-inositol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

: 133163-53-8
O-(2-azido-3,4,6-tri-O-benzyl-2-deoxy-α-D-glucopyranosyl)-(1->4)-1,5,6-tri-O-benzyl-L-myo-inositol

: 106-95-6
allyl bromide

: O-(2-azido-3,4,6-tri-O-benzyl-2-deoxy-α-D-glucopyranosyl)-(1->6)-2-O-allyl-3,4,5-tri-O-benzyl-D-myo-inositol

: 760987-55-1
O-(2-azido-3,4,6-tri-O-benzyl-2-deoxy-α-D-glucopyranosyl)-(1->6)-1-O-allyl-3,4,6-tri-O-benzyl-D-myo-inositol

Guidance literature:: O-(2-azido-3,4,6-tri-O-benzyl-2-deoxy-α-D-glucopyranosyl)-(1->4)-1,5,6-tri-O-benzyl-L-myo-inositol; With di(n-butyl)tin oxide; In toluene; for 24h; Heating;

allyl bromide; With tetra-(n-butyl)ammonium iodide; In toluene; for 2h; Further stages.; Heating;
DOI:10.1002/chem.200500833

Reference yield:

: 1053696-21-1
(2R,3R,4R,5S,6R)-2-[(1S,2R,3S,4S,5R,6S)-2-Allyloxy-4,5,6-tris-benzyloxy-3-(3',4'-dimethoxy-biphenyl-4-ylmethoxy)-cyclohexyloxy]-3-azido-4,5-bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran

: 760987-55-1
O-(2-azido-3,4,6-tri-O-benzyl-2-deoxy-α-D-glucopyranosyl)-(1->6)-1-O-allyl-3,4,6-tri-O-benzyl-D-myo-inositol

Guidance literature:: With water; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; at 20 ℃; for 2h;
DOI:10.1039/b407324j

Reference yield:

: 100-39-0
benzyl bromide

: 760987-55-1
O-(2-azido-3,4,6-tri-O-benzyl-2-deoxy-α-D-glucopyranosyl)-(1->6)-1-O-allyl-3,4,6-tri-O-benzyl-D-myo-inositol

Guidance literature:: Multi-step reaction with 3 steps

1.1: BuNI; NaH / dimethylformamide / 0.33 h / 0 °C

1.2: 86 percent / dimethylformamide / 5 h / 0 - 20 °C

2.1: Bu₄NBr; K₃PO₄ / Pd(OAc)2 / ethanol

3.1: 45 mg / DDQ; H₂O / CH₂Cl₂ / 2 h / 20 °C

With potassium phosphate; tetrabutylammomium bromide; water; tetra-(n-butyl)ammonium iodide; sodium hydride; 2,3-dicyano-5,6-dichloro-p-benzoquinone; palladium diacetate; In ethanol; dichloromethane; N,N-dimethyl-formamide; 2.1: Suzuki-Miyaura coupling;
DOI:10.1039/b407324j