(E)-2-((tert-butyldimethylsilyl)oxy)-2-(3-((tert-butyldimethylsilyl)oxy)allyl)cyclohexanone

Base Information

Chemical Name:(E)-2-((tert-butyldimethylsilyl)oxy)-2-(3-((tert-butyldimethylsilyl)oxy)allyl)cyclohexanone
CAS No.:1350520-34-1
Molecular Formula:C₂₃H₃₄O₄Si
Molecular Weight:402.606
Hs Code.:

Synonyms:(E)-2-((tert-butyldimethylsilyl)oxy)-2-(3-((tert-butyldimethylsilyl)oxy)allyl)cyclohexanone

Suppliers and Price of (E)-2-((tert-butyldimethylsilyl)oxy)-2-(3-((tert-butyldimethylsilyl)oxy)allyl)cyclohexanone

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (E)-2-((tert-butyldimethylsilyl)oxy)-2-(3-((tert-butyldimethylsilyl)oxy)allyl)cyclohexanone

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Technology Process of (E)-2-((tert-butyldimethylsilyl)oxy)-2-(3-((tert-butyldimethylsilyl)oxy)allyl)cyclohexanone

There total 6 articles about (E)-2-((tert-butyldimethylsilyl)oxy)-2-(3-((tert-butyldimethylsilyl)oxy)allyl)cyclohexanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 2495-35-4,25036-21-9
benzylacrylate

: 2-allyl-2-((tert-butyldimethylsilyl)oxy)cyclohexanone

: 1350520-34-1
(E)-2-((tert-butyldimethylsilyl)oxy)-2-(3-((tert-butyldimethylsilyl)oxy)allyl)cyclohexanone

Guidance literature:: With Hoveyda-Grubbs catalyst second generation; In dichloromethane; at 40 ℃; for 24h; Inert atmosphere;
DOI:10.1021/ol2030422

Reference yield:

: 86170-45-8
benzyl 3-butenoate

: 2-allyl-2-((tert-butyldimethylsilyl)oxy)cyclohexanone

: 1350520-34-1
(E)-2-((tert-butyldimethylsilyl)oxy)-2-(3-((tert-butyldimethylsilyl)oxy)allyl)cyclohexanone

: (Z)-benzyl 5-(1-((tert-butyldimethylsilyl)oxy)-2-oxocyclohexyl)pent-3-enoate

Guidance literature:: With Hoveyda-Grubbs catalyst second generation; In dichloromethane; at 40 ℃; for 48h; optical yield given as %de; Inert atmosphere;
DOI:10.1021/ol2030422

Reference yield:

: 116608-34-5
2-{(tert-butyldimethylsilyl)oxy}cyclohex-2-en-1-one

: 1350520-34-1
(E)-2-((tert-butyldimethylsilyl)oxy)-2-(3-((tert-butyldimethylsilyl)oxy)allyl)cyclohexanone

Guidance literature:: Multi-step reaction with 3 steps

1: diethyl ether / 1 h / 0 °C / Inert atmosphere

2: potassium carbonate / methanol / 0.25 h / 20 °C / Inert atmosphere

3: Hoveyda-Grubbs catalyst second generation / dichloromethane / 24 h / 40 °C / Inert atmosphere

With Hoveyda-Grubbs catalyst second generation; potassium carbonate; In methanol; diethyl ether; dichloromethane;
DOI:10.1021/ol2030422