Benzyl acrylate

Base Information

• Chemical Name: Benzyl acrylate
• CAS No.: 2495-35-4
• Deprecated CAS: 1426230-24-1,2061966-59-2,1933490-62-0
• Molecular Formula: C10H10O2
• Molecular Weight: 162.188
• Hs Code.: 29161290
• European Community (EC) Number: 219-673-9
• NSC Number: 20964
• DSSTox Substance ID: DTXSID1062467
• Nikkaji Number: J71.666I
• Wikidata: Q72440529
• Mol file: 2495-35-4.mol

Synonyms:Benzyl acrylate;2495-35-4;Benzyl prop-2-enoate;Benzylacrylate;2-Propenoic acid, phenylmethyl ester;acrylic acid benzyl ester;benzyl 2-propenoate;Sartomer SR 432;Acrylic acid, benzyl ester;SR 432;EINECS 219-673-9;MFCD00048147;NSC 20964;AI3-03836;Benzyl Acrylate (Stabilized with 50ppm of MEHQ);Benzyl acrylate stab. with ca 150ppm 4-methoxyphenol;Benzyl acrylate,~99%(2.2 cps(typical));Fancryl FA-BZA;Acrylic acid benzyl;Acrylicacidbenzylester;Melcril 4085;FA-BZA;SCHEMBL34054;SCHEMBL8071132;DTXSID1062467;NSC20964;AB6137;NSC-20964;AKOS005207054;Benzylacrylate,(Acrylicacidbenzylester);AM62651;CS-W020607;Benzyl Acrylate (stabilized with MEHQ);BP-30234;MS-20517;SY004327;A5085;B4627;FT-0622766;BENZYL ACRYLATE( STABILIZED WITH MEHQ);EN300-123905;J-015747

Chemical Property of Benzyl acrylate

Chemical Property:

• Vapor Pressure: 0.0725mmHg at 25°C
• Melting Point: 214-216 °C
• Refractive Index: 1.5180
• Boiling Point: 228.7 °C at 760 mmHg
• Flash Point: 115.5 °C
• PSA: 26.30000
• Density: 1.054 g/cm³
• LogP: 1.91580
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature
• Water Solubility.: Miscible with organic solvents and water.
• XLogP3: 2.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 162.068079557
• Heavy Atom Count: 12
• Complexity: 157

Purity/Quality:

99.9% ^*data from raw suppliers

BenzylAcrylate(Stabilizedwith50ppmofMEHQ) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): R36/37/38:Irritating to eyes, respiratory system and skin.; R51/53:Toxic to aquatic organisms, may cause long-term advers
• Hazard Codes: R36/37/38:Irritating to eyes, respiratory system and skin.; R51/53:Toxic to aquatic organisms, may cause long-term advers
• Statements: 36/37/38
• Safety Statements: 26-36/37/39-61-28

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CC(=O)OCC1=CC=CC=C1
• Uses: Benzyl Acrylate, is a reagent that can be used in the preparation of 2-(Phosphonomethyl)pentanedioic Acid (P353900), a selective glutamate carboxypeptidase 2 (GCP-II) inhibitor. It can also be used in the preparation of high refractive index polyacrylates. Preparation of high refractive index polyacrylates.Benzyl acrylate is used in the preparation of heptanoic acid benzyl ester. It is used to prepare polybenzylacrylate using azobisisobutyronitrile as initiator.

Technology Process of Benzyl acrylate

There total 50 articles about Benzyl acrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

benzyl chloride (100-44-7) + acrylic acid (79-10-7) → benzylacrylate (2495-35-4,25036-21-9)

Guidance literature:

With potassium carbonate; In N,N-dimethyl-formamide; at 100 ℃; for 3h;

DOI:10.1021/ol050040d

Reference yield: 99.0%

acrylic acid methyl ester (292638-85-8,9003-21-8,96-33-3) + benzyl alcohol (100-51-6,185532-71-2) → benzylacrylate (2495-35-4,25036-21-9)

Guidance literature:

With dmap; oxo[hexa(trifluoroacetato)]tetrazinc; In neat (no solvent); at 80 ℃; for 24h; Reagent/catalyst; Solvent; chemoselective reaction; Inert atmosphere; Schlenk technique;

DOI:10.1002/ejoc.201600737

Reference yield: 99.0%

acrylic acid (79-10-7) + benzyl alcohol (100-51-6,185532-71-2) → benzylacrylate (2495-35-4,25036-21-9)

Guidance literature:

tetrachlorobis(tetrahydrofuran)hafnium(IV); In benzene; for 40h; Heating;

DOI:10.1016/S0040-4020(02)00966-3

upstream raw materials:

3-chloro-propionic acid benzyl ester

acrylic acid

benzyl alcohol

acryloyl chloride

Downstream raw materials:

2-[(1R)-1-(2-benzyloxycarbonyl-ethyl)-7-oxo-(1rH,5cH)-4-thia-2,6-diaza-bicyclo[3.2.0]hept-2-en-6-yl]-3-methyl-but-2-enoic acid benzyl ester

dimethyl 1,2-cyclohexanedicarboxylate

dimethyl cyclohexane-1,3-dicarboxylate

dimethyl 3-cyclohexene-1,2-dicarboxylate