2,3-di-O-benzoyl-6-O-(tert-butyldiphenylsilyl)-4-deoxy-α-D-xylo-hexopyranosyl chloride

Base Information

Chemical Name:2,3-di-O-benzoyl-6-O-(tert-butyldiphenylsilyl)-4-deoxy-α-D-xylo-hexopyranosyl chloride
CAS No.:131291-13-9
Molecular Formula:C₃₆H₃₇ClO₆Si
Molecular Weight:629.225
Hs Code.:

Synonyms:2,3-di-O-benzoyl-6-O-(tert-butyldiphenylsilyl)-4-deoxy-α-D-xylo-hexopyranosyl chloride

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Chemical Property of 2,3-di-O-benzoyl-6-O-(tert-butyldiphenylsilyl)-4-deoxy-α-D-xylo-hexopyranosyl chloride

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Technology Process of 2,3-di-O-benzoyl-6-O-(tert-butyldiphenylsilyl)-4-deoxy-α-D-xylo-hexopyranosyl chloride

There total 3 articles about 2,3-di-O-benzoyl-6-O-(tert-butyldiphenylsilyl)-4-deoxy-α-D-xylo-hexopyranosyl chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 131291-10-6
methyl 2,3-di-O-benzoyl-6-O-(tert-butyldiphenylsilyl)-4-deoxy-β-D-xylo-hexopyranoside

: 131291-13-9
2,3-di-O-benzoyl-6-O-(tert-butyldiphenylsilyl)-4-deoxy-α-D-xylo-hexopyranosyl chloride

Guidance literature:: With Dichloromethyl methyl ether; zinc(II) chloride; In chloroform; at 55 ℃; for 1.5h;
DOI:10.1016/0008-6215(90)84033-Q

Reference yield:

: 131291-08-2
methyl 2,3-di-O-benzoyl-6-O-(tert-butyldiphenylsilyl)-β-D-galactopyranoside

: 131291-13-9
2,3-di-O-benzoyl-6-O-(tert-butyldiphenylsilyl)-4-deoxy-α-D-xylo-hexopyranosyl chloride

Guidance literature:: Multi-step reaction with 3 steps

1: 94 percent / toluene / 15 h / 100 °C

2: 95 percent / tributyltin hydride / toluene / 0.75 h / Heating

3: 85 percent / dichloromethyl methyl ether, zinc chloride / CHCl₃ / 1.5 h / 55 °C

With Dichloromethyl methyl ether; tri-n-butyl-tin hydride; zinc(II) chloride; In chloroform; toluene;
DOI:10.1016/0008-6215(90)84033-Q

Reference yield:

: 131291-09-3
methyl 2,3-di-O-benzoyl-6-O-(tert-butyldiphenylsilyl)-4-O-(imidazol-1-ylthiocarbonyl)-β-D-galactopyranoside

: 131291-13-9
2,3-di-O-benzoyl-6-O-(tert-butyldiphenylsilyl)-4-deoxy-α-D-xylo-hexopyranosyl chloride

Guidance literature:: Multi-step reaction with 2 steps

1: 95 percent / tributyltin hydride / toluene / 0.75 h / Heating

2: 85 percent / dichloromethyl methyl ether, zinc chloride / CHCl₃ / 1.5 h / 55 °C

With Dichloromethyl methyl ether; tri-n-butyl-tin hydride; zinc(II) chloride; In chloroform; toluene;
DOI:10.1016/0008-6215(90)84033-Q