2,6-Diiodonaphthalene

Base Information

• Chemical Name: 2,6-Diiodonaphthalene
• CAS No.: 36316-88-8
• Molecular Formula: C10H6I2
• Molecular Weight: 379.967
• DSSTox Substance ID: DTXSID70189851
• Nikkaji Number: J1.618.406C
• Wikidata: Q83062062
• Mol file: 36316-88-8.mol

Synonyms:2,6-diiodonaphthalene;36316-88-8;SCHEMBL1297632;DTXSID70189851;JEVDBSPYZIVTGM-UHFFFAOYSA-N;CS-0085713;FT-0725945;E84286

Chemical Property of 2,6-Diiodonaphthalene

Chemical Property:

• Vapor Pressure: 9.21E-06mmHg at 25°C
• Boiling Point: 384.2°Cat760mmHg
• Flash Point: 204.3°C
• PSA: 0.00000
• Density: 2.265g/cm³
• LogP: 4.04900
• XLogP3: 4.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 379.85590
• Heavy Atom Count: 12
• Complexity: 140

Purity/Quality:

99.90% ^*data from raw suppliers

2,6-Diiodonaphthalene ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC2=C(C=CC(=C2)I)C=C1I

Technology Process of 2,6-Diiodonaphthalene

There total 1 articles about 2,6-Diiodonaphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

naphthalene (91-20-3,71998-51-1,72931-45-4) → 2-iodonaphthalene (612-55-5) + 1-Iodonaphthalene (90-14-2) + 2,6-diiodonaphthalene (36316-88-8)

Guidance literature:

With faujasite zeolite KX; iodine; oxygen; at 250 ℃; Product distribution; Mechanism; Thermodynamic data; Ea; var. temp., iodine conc., oxygen conc., and zeolite modifications; also 2-iodonaphthalene;

DOI:10.1006/jcat.1994.1129

Reference yield: 54.0%

2,4,5-trimethylbenzaldehyde (5779-72-6) + 2,6-diiodonaphthalene (36316-88-8) → 6,6'-(naphthalene-2,6-diylbis(methylene))bis(3,4-dimethylbenzaldehyde)

Guidance literature:

With palladium diacetate; silver trifluoroacetate; acetic acid; glycine; In water; at 100 ℃; for 36h; Sealed tube;

DOI:10.1021/acs.orglett.8b03359

Reference yield: 44.0%

2,6-diiodonaphthalene (36316-88-8) + 2,4-dimethylbenzaldehyde (15764-16-6) → 4-methyl-2-((9-methyltetraphen-3-yl)methyl)benzaldehyde

Guidance literature:

With palladium diacetate; silver trifluoroacetate; acetic acid; glycine; In water; at 100 ℃; for 36h; Sealed tube;

DOI:10.1021/acs.orglett.8b03359

upstream raw materials:

naphthalene

Refernces