(2E,6E)-9-Benzenesulfonyl-3,7-dimethyl-8-(tetrahydro-pyran-2-yloxy)-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,6-dien-1-ol

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Chemical Name:(2E,6E)-9-Benzenesulfonyl-3,7-dimethyl-8-(tetrahydro-pyran-2-yloxy)-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,6-dien-1-ol
CAS No.:103905-10-8
Molecular Formula:C₃₁H₄₆O₅S
Molecular Weight:530.769
Hs Code.:

Synonyms:(2E,6E)-9-Benzenesulfonyl-3,7-dimethyl-8-(tetrahydro-pyran-2-yloxy)-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,6-dien-1-ol

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Chemical Property of (2E,6E)-9-Benzenesulfonyl-3,7-dimethyl-8-(tetrahydro-pyran-2-yloxy)-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,6-dien-1-ol

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Technology Process of (2E,6E)-9-Benzenesulfonyl-3,7-dimethyl-8-(tetrahydro-pyran-2-yloxy)-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,6-dien-1-ol

There total 6 articles about (2E,6E)-9-Benzenesulfonyl-3,7-dimethyl-8-(tetrahydro-pyran-2-yloxy)-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,6-dien-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 103905-07-3
1-acetoxy-3,7-dimethyl-8-(tetrahydropyran-2-yl)oxy-9-phenylsulfonyl-9-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2(E),6(E)-nonadiene

: 103905-10-8
(2E,6E)-9-Benzenesulfonyl-3,7-dimethyl-8-(tetrahydro-pyran-2-yloxy)-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,6-dien-1-ol

Guidance literature:: With potassium tert-butylate; In toluene; for 2h; Ambient temperature;
DOI:10.1021/jo00370a017

Reference yield:

: 105-87-3,8022-83-1
3,7-dimethyl-2E,6-octadien-1-yl acetate

: 103905-10-8
(2E,6E)-9-Benzenesulfonyl-3,7-dimethyl-8-(tetrahydro-pyran-2-yloxy)-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,6-dien-1-ol

Guidance literature:: Multi-step reaction with 5 steps

1: SeO₂, salicylic acid, tert-butyl hydroperoxide / CH₂Cl₂ / 27 h / Ambient temperature

2: PDC / CH₂Cl₂ / 10 h / Ambient temperature

3: 1.) n-BuLi / 1.) THF, -78 deg C, 2 h, 2.) THF, -78 deg C, 3 h

4: 99 percent / p-toluenesulfonic acid / CH₂Cl₂ / 3 h / Ambient temperature

5: 89 percent / t-BuOK / toluene / 2 h / Ambient temperature

With tert.-butylhydroperoxide; dipyridinium dichromate; n-butyllithium; selenium(IV) oxide; potassium tert-butylate; toluene-4-sulfonic acid; salicylic acid; In dichloromethane; toluene;
DOI:10.1021/jo00370a017

Reference yield:

: 37905-03-6
8-hydroxygeranyl acetate

: 103905-10-8
(2E,6E)-9-Benzenesulfonyl-3,7-dimethyl-8-(tetrahydro-pyran-2-yloxy)-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,6-dien-1-ol

Guidance literature:: Multi-step reaction with 4 steps

1: PDC / CH₂Cl₂ / 10 h / Ambient temperature

2: 1.) n-BuLi / 1.) THF, -78 deg C, 2 h, 2.) THF, -78 deg C, 3 h

3: 99 percent / p-toluenesulfonic acid / CH₂Cl₂ / 3 h / Ambient temperature

4: 89 percent / t-BuOK / toluene / 2 h / Ambient temperature

With dipyridinium dichromate; n-butyllithium; potassium tert-butylate; toluene-4-sulfonic acid; In dichloromethane; toluene;
DOI:10.1021/jo00370a017