benzyl 2,4-diazido-3-O-benzoyl-2,4,6-trideoxy-β-D-mannopyranoside

Base Information

• Chemical Name: benzyl 2,4-diazido-3-O-benzoyl-2,4,6-trideoxy-β-D-mannopyranoside
• CAS No.: 396659-42-0
• Molecular Formula: C₂₀H₂₀N₆O₄
• Molecular Weight: 408.417
• Mol file: 396659-42-0.mol

Synonyms:benzyl 2,4-diazido-3-O-benzoyl-2,4,6-trideoxy-β-D-mannopyranoside

Chemical Property of benzyl 2,4-diazido-3-O-benzoyl-2,4,6-trideoxy-β-D-mannopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of benzyl 2,4-diazido-3-O-benzoyl-2,4,6-trideoxy-β-D-mannopyranoside

There total 4 articles about benzyl 2,4-diazido-3-O-benzoyl-2,4,6-trideoxy-β-D-mannopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Benzoic acid (2R,3R,4S,5S,6R)-2-benzyloxy-6-methyl-3,5-bis-trifluoromethanesulfonyloxy-tetrahydro-pyran-4-yl ester → benzyl 2,4-diazido-3-O-benzoyl-2,4,6-trideoxy-β-D-mannopyranoside (396659-42-0)

Guidance literature:

With tetrabutylammoniun azide; In toluene; at 100 ℃;

DOI:10.1016/S0008-6215(01)00041-6

Reference yield:

benzoyl chloride (98-88-4) → benzyl 2,4-diazido-3-O-benzoyl-2,4,6-trideoxy-β-D-mannopyranoside (396659-42-0)

Guidance literature:

Multi-step reaction with 3 steps

1.1: Bu₂SnO / benzene / 5 h / Heating

1.2: 61 percent / benzene / 2 h / 0 - 5 °C

2.1: pyridine / CH₂Cl₂ / 1 h / 0 °C

3.1: 2.12 g / tetrabutylammonium azide / toluene / 2.5 h / 65 - 105 °C

With pyridine; tetrabutylammoniun azide; di(n-butyl)tin oxide; In dichloromethane; toluene; benzene;

DOI:10.1016/S0008-6215(01)00235-X

Reference yield:

benzyl β-D-fucopyranoside (78120-06-6) → benzyl 2,4-diazido-3-O-benzoyl-2,4,6-trideoxy-β-D-mannopyranoside (396659-42-0)

Guidance literature:

Multi-step reaction with 3 steps

1.1: Bu₂SnO / benzene / 5 h / Heating

1.2: 61 percent / benzene / 2 h / 0 - 5 °C

2.1: pyridine / CH₂Cl₂ / 1 h / 0 °C

3.1: 2.12 g / tetrabutylammonium azide / toluene / 2.5 h / 65 - 105 °C

With pyridine; tetrabutylammoniun azide; di(n-butyl)tin oxide; In dichloromethane; toluene; benzene;

DOI:10.1016/S0008-6215(01)00235-X

upstream raw materials:

benzoyl chloride

benzyl β-D-fucopyranoside

benzyl β-D-fucopyranoside-3-O-benzoate

Downstream raw materials:

benzyl 2,4-diacetamido-2,4,6-trideoxy-β-D-mannopyranoside