{Rh2(μ-O2CMe)2{(C6H4)PPh2}{(C6H4)P(C6H5)2}(HO2CMe)2}

Base Information

• Chemical Name: {Rh2(μ-O2CMe)2{(C6H4)PPh2}{(C6H4)P(C6H5)2}(HO2CMe)2}
• CAS No.: 91837-70-6
• Molecular Formula: C₄₄H₄₂O₈P₂Rh₂
• Molecular Weight: 966.571
• Mol file: 91837-70-6.mol

Synonyms:{Rh2(μ-O2CMe)2{(C6H4)PPh2}{(C6H4)P(C6H5)2}(HO2CMe)2}

Chemical Property of {Rh2(μ-O2CMe)2{(C6H4)PPh2}{(C6H4)P(C6H5)2}(HO2CMe)2}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {Rh2(μ-O2CMe)2{(C6H4)PPh2}{(C6H4)P(C6H5)2}(HO2CMe)2}

There total 8 articles about {Rh2(μ-O2CMe)2{(C6H4)PPh2}{(C6H4)P(C6H5)2}(HO2CMe)2} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

tetra[μ-acetato-bis(methanol)]dirhodium → {Rh2(μ-O2CMe)2{(C6H4)PPh2}{(C6H4)P(C6H5)2}(HO2CMe)2} (91837-70-6)

Guidance literature:

With triphenylphosphine; In acetic acid; under N2, refluxed for l5 min, concd. to half its initial vol.; solid deposited was filtered off;

Reference yield: 45.0%

[Rh2(CH3CO2)4(MeOH)2] → {Rh2(μ-O2CMe)2{(C6H4)PPh2}{(C6H4)P(C6H5)2}(HO2CMe)2} (91837-70-6) + Rh2(O2CCH3)2{(C6H4)P(C6H5)2}2(HO2CCH3)2 (138459-78-6)

Guidance literature:

With P(C₆H₅)3; In toluene; under Ar, molar educt ratio Rh-compd.:PPh3 = 1:4, refluxed for 2 h; evapn. to dryness, column chromy. (silica gel/acetone-hexane from 1:10 to 1:3), sepn. of the two compds.: concn. to dryness under vac., dissolved in CH2Cl2/acetic acid, addn. of hexane; elem. anal.;

Reference yield:

Rh2(O2CCH3)3{(C6H4)P(C6H5)2}(P(C6H5)3)(H2O) (138459-71-9) → {Rh2(μ-O2CMe)2{(C6H4)PPh2}{(C6H4)P(C6H5)2}(HO2CMe)2} (91837-70-6)

Guidance literature:

With acetic acid; In toluene; at different temp. with different catalysts (acetic acid, triflic acid or Na acetate); Kinetics;

DOI:10.1039/DT9940000545

upstream raw materials:

{Rh2(O2CMe)(μ-O2CMe)2{(C6H4)PPh2}{P(C6H5)3}(HO2CMe)}

Rh₂(O₂CCH₃)3{(C₆H₄)P(C₆H₅)2}(P(C₆H₅)3)(H₂O)

acetic acid

triphenylphosphine

Downstream raw materials:

Rh₂(acetato)2[(C₆H₄)P(C₆H₅)2]2(H₂O)2

[Rh₂(OCOCH₃)2(P(C₆H₅)3)2((C₆H₄)P(C₆H₅)2)2]

Rh₂(acetato)2[(C₆H₄)P(C₆H₅)2]2Py₂

Rh₂(C₄H₄NO₂)2(C₆H₄P(C₆H₅)2)2