4-(7,12-dibromo-5,5,10,10,15,15-hexahexyl-10,15-dihydro-5H-diindeno[1,2-a;1',2'-c]fluoren-2-yl)-benzaldehyde

Base Information

• Chemical Name: 4-(7,12-dibromo-5,5,10,10,15,15-hexahexyl-10,15-dihydro-5H-diindeno[1,2-a;1',2'-c]fluoren-2-yl)-benzaldehyde
• CAS No.: 866352-92-3
• Molecular Formula: C₇₀H₉₂Br₂O
• Molecular Weight: 1109.31
• Mol file: 866352-92-3.mol

Synonyms:4-(7,12-dibromo-5,5,10,10,15,15-hexahexyl-10,15-dihydro-5H-diindeno[1,2-a;1',2'-c]fluoren-2-yl)-benzaldehyde

Chemical Property of 4-(7,12-dibromo-5,5,10,10,15,15-hexahexyl-10,15-dihydro-5H-diindeno[1,2-a;1',2'-c]fluoren-2-yl)-benzaldehyde

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-(7,12-dibromo-5,5,10,10,15,15-hexahexyl-10,15-dihydro-5H-diindeno[1,2-a;1',2'-c]fluoren-2-yl)-benzaldehyde

There total 2 articles about 4-(7,12-dibromo-5,5,10,10,15,15-hexahexyl-10,15-dihydro-5H-diindeno[1,2-a;1',2'-c]fluoren-2-yl)-benzaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

4-formylphenylboronic acid, (87199-17-5) + 2,7,12-tribromo-5,5',10,10',15,15'-hexahexyltruxene (600172-86-9) → 4-(7,12-dibromo-5,5,10,10,15,15-hexahexyl-10,15-dihydro-5H-diindeno[1,2-a;1',2'-c]fluoren-2-yl)-benzaldehyde (866352-92-3)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate; In tetrahydrofuran; Heating;

DOI:10.1021/ol051221i

Reference yield: 34.0%

4-formylphenylboronic acid, (87199-17-5) + 2,7,12-tribromo-5,5',10,10',15,15'-hexahexyltruxene (600172-86-9) → 4-(7,12-dibromo-5,5,10,10,15,15-hexahexyl-10,15-dihydro-5H-diindeno[1,2-a;1',2'-c]fluoren-2-yl)-benzaldehyde (866352-92-3) + C77H97BrO2 + C84H102O3

Guidance literature:

With sodium carbonate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; water; for 10h; Heating;

DOI:10.1021/ol0616283

Reference yield: 92.0%

4-(7,12-dibromo-5,5,10,10,15,15-hexahexyl-10,15-dihydro-5H-diindeno[1,2-a;1',2'-c]fluoren-2-yl)-benzaldehyde (866352-92-3) + phenylboronic acid (98-80-6) → 4-(5,5,10,10,15,15-hexahexyl-7,12-diphenyl-10,15-dihydro-5H-diindeno[1,2-a;1',2'-c]fluoren-2-yl)-benzaldehyde

Guidance literature:

With sodium carbonate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; water; Heating;

DOI:10.1021/ol0616283

upstream raw materials:

4-formylphenylboronic acid,

2,7,12-tribromo-5,5',10,10',15,15'-hexahexyltruxene

Downstream raw materials:

4-(5,5,10,10,15,15-hexahexyl-7,12-di-thiophen-2-yl-10,15-dihydro-5H-diindeno[1,2-a;1',2'-c]fluoren-2-yl)-benzaldehyde

4-[7,12-bis-(5-bromo-thiophen-2-yl)-5,5,10,10,15,15-hexahexyl-10,15-dihydro-5H-diindeno[1,2-a;1',2'-c]fluoren-2-yl]-benzaldehyde

C₁₆₈H₁₈₆N₄O