(-)-(2S,3S)-4-O-benzoyl-2,3-dihydroxy-2,3-O-isopropylidene-2-methylbutanal

Base Information

Chemical Name:(-)-(2S,3S)-4-O-benzoyl-2,3-dihydroxy-2,3-O-isopropylidene-2-methylbutanal
CAS No.:130353-28-5
Molecular Formula:C₁₅H₁₈O₅
Molecular Weight:278.305
Hs Code.:

Synonyms:(-)-(2S,3S)-4-O-benzoyl-2,3-dihydroxy-2,3-O-isopropylidene-2-methylbutanal

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (-)-(2S,3S)-4-O-benzoyl-2,3-dihydroxy-2,3-O-isopropylidene-2-methylbutanal

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Technology Process of (-)-(2S,3S)-4-O-benzoyl-2,3-dihydroxy-2,3-O-isopropylidene-2-methylbutanal

There total 8 articles about (-)-(2S,3S)-4-O-benzoyl-2,3-dihydroxy-2,3-O-isopropylidene-2-methylbutanal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 130353-27-4
(-)-(2S,3R)-1-O-benzoyl-2,3-dihydroxy-2,3-O-isopropylidene-2-methylpent-4-ene

: 130353-28-5
(-)-(2S,3S)-4-O-benzoyl-2,3-dihydroxy-2,3-O-isopropylidene-2-methylbutanal

Guidance literature:: With sodium periodate; osmium(VIII) oxide; In ethanol; water; Ambient temperature;
DOI:10.1021/jo00001a073

Reference yield:

: 130464-15-2
(-)-5-iodo-2,3-O-isopropylidene-2-C-methyl-D-ribolactone

: 130353-28-5
(-)-(2S,3S)-4-O-benzoyl-2,3-dihydroxy-2,3-O-isopropylidene-2-methylbutanal

Guidance literature:: Multi-step reaction with 5 steps

1: 95 percent / Zn, HOAc / H₂O; tetrahydrofuran / 3 h / Ambient temperature

2: diethyl ether

3: 98 percent / LiAlH₄ / tetrahydrofuran / Ambient temperature

4: 95 percent / pyridine / 1 h / Ambient temperature

5: 86 percent / OsO₄, NaIO₄ / ethanol; H₂O; various solvent(s) / Ambient temperature

With pyridine; sodium periodate; osmium(VIII) oxide; lithium aluminium tetrahydride; acetic acid; zinc; In tetrahydrofuran; diethyl ether; ethanol; water;
DOI:10.1021/jo00001a073

Reference yield:

: 109715-12-0
2,3-O-Isopropyliden-2-C-methyl-5-O-p-toluolsulfonyl-D-ribo-pentonsaeure-γ-lacton

: 130353-28-5
(-)-(2S,3S)-4-O-benzoyl-2,3-dihydroxy-2,3-O-isopropylidene-2-methylbutanal

Guidance literature:: Multi-step reaction with 6 steps

1: 95 percent / NaI / butan-2-one / 3 h / Heating

2: 95 percent / Zn, HOAc / H₂O; tetrahydrofuran / 3 h / Ambient temperature

3: diethyl ether

4: 98 percent / LiAlH₄ / tetrahydrofuran / Ambient temperature

5: 95 percent / pyridine / 1 h / Ambient temperature

6: 86 percent / OsO₄, NaIO₄ / ethanol; H₂O; various solvent(s) / Ambient temperature

With pyridine; sodium periodate; osmium(VIII) oxide; lithium aluminium tetrahydride; acetic acid; sodium iodide; zinc; In tetrahydrofuran; diethyl ether; ethanol; water; butanone;
DOI:10.1021/jo00001a073