5-(4-carboxyphenylethynyl)-10,15-bis(bis(4-methylphenyl)amino)-20-(2,4,6-trimethylphenyl)porphyrinatozinc (II)

Base Information

Chemical Name:5-(4-carboxyphenylethynyl)-10,15-bis(bis(4-methylphenyl)amino)-20-(2,4,6-trimethylphenyl)porphyrinatozinc (II)
CAS No.:1333519-51-9
Molecular Formula:C₆₄H₅₂N₆O₂Zn
Molecular Weight:1002.55
Hs Code.:

Synonyms:5-(4-carboxyphenylethynyl)-10,15-bis(bis(4-methylphenyl)amino)-20-(2,4,6-trimethylphenyl)porphyrinatozinc (II)

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Chemical Property of 5-(4-carboxyphenylethynyl)-10,15-bis(bis(4-methylphenyl)amino)-20-(2,4,6-trimethylphenyl)porphyrinatozinc (II)

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Technology Process of 5-(4-carboxyphenylethynyl)-10,15-bis(bis(4-methylphenyl)amino)-20-(2,4,6-trimethylphenyl)porphyrinatozinc (II)

There total 5 articles about 5-(4-carboxyphenylethynyl)-10,15-bis(bis(4-methylphenyl)amino)-20-(2,4,6-trimethylphenyl)porphyrinatozinc (II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 15.0%

: 620-93-9
di-p-tolylamine

: 1333519-50-8
5-(4-methoxycarbonylphenyl)-10-(2,4,6-trimethylphenyl)porphyrinatozinc (II)

: 1333519-51-9
5-(4-carboxyphenylethynyl)-10,15-bis(bis(4-methylphenyl)amino)-20-(2,4,6-trimethylphenyl)porphyrinatozinc (II)

Guidance literature:: di-p-tolylamine; 5-(4-methoxycarbonylphenyl)-10-(2,4,6-trimethylphenyl)porphyrinatozinc (II); With sodium tetrachloroaurate(III) dihydrate; [bis(acetoxy)iodo]benzene; In dichloromethane; at 20 ℃;

With sodium hydroxide; In tetrahydrofuran; water; for 12h; Reflux;

With zinc(II) acetate dihydrate; In methanol; chloroform; at 20 ℃; for 1h;
DOI:10.1002/chem.201303460

Reference yield: 14.5%

: zinc acetate pentahydrate

: 620-93-9
di-p-tolylamine

: 1333519-50-8
5-(4-methoxycarbonylphenyl)-10-(2,4,6-trimethylphenyl)porphyrinatozinc (II)

: 1333519-51-9
5-(4-carboxyphenylethynyl)-10,15-bis(bis(4-methylphenyl)amino)-20-(2,4,6-trimethylphenyl)porphyrinatozinc (II)

Guidance literature:: di-p-tolylamine; 5-(4-methoxycarbonylphenyl)-10-(2,4,6-trimethylphenyl)porphyrinatozinc (II); With sodium tetrachloroaurate(III) dihydrate; [bis(acetoxy)iodo]benzene; In dichloromethane; at 20 ℃; for 0.25h;

With water; sodium hydroxide; In tetrahydrofuran; for 1h; Reflux;

zinc acetate pentahydrate; In methanol; chloroform; at 20 ℃; for 1h;

Reference yield:

: 1571-08-0
methyl 4-formylbenzoate

: 1333519-51-9
5-(4-carboxyphenylethynyl)-10,15-bis(bis(4-methylphenyl)amino)-20-(2,4,6-trimethylphenyl)porphyrinatozinc (II)

Guidance literature:: Multi-step reaction with 3 steps

1.1: boron trifluoride diethyl etherate / chloroform / 1.5 h / 20 °C / Inert atmosphere

1.2: 1.5 h / 20 °C / Inert atmosphere

2.1: zinc(II) acetate dihydrate / chloroform; methanol / 2 h / 20 °C

3.1: [bis(acetoxy)iodo]benzene; sodium tetrachloroaurate(III) dihydrate / dichloromethane / 20 °C

3.2: 12 h / Reflux

3.3: 1 h / 20 °C

With sodium tetrachloroaurate(III) dihydrate; [bis(acetoxy)iodo]benzene; boron trifluoride diethyl etherate; zinc(II) acetate dihydrate; In methanol; dichloromethane; chloroform;
DOI:10.1002/chem.201303460