benzyl 5-deoxy-5-(N-diphenylphosphinoyl)amino-2,3-O-isopropylidene-β-D-ribofuranoside

Base Information

Chemical Name:benzyl 5-deoxy-5-(N-diphenylphosphinoyl)amino-2,3-O-isopropylidene-β-D-ribofuranoside
CAS No.:328533-47-7
Molecular Formula:C₂₇H₃₀NO₇P
Molecular Weight:511.511
Hs Code.:

Synonyms:benzyl 5-deoxy-5-(N-diphenylphosphinoyl)amino-2,3-O-isopropylidene-β-D-ribofuranoside

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Chemical Property of benzyl 5-deoxy-5-(N-diphenylphosphinoyl)amino-2,3-O-isopropylidene-β-D-ribofuranoside

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Technology Process of benzyl 5-deoxy-5-(N-diphenylphosphinoyl)amino-2,3-O-isopropylidene-β-D-ribofuranoside

There total 3 articles about benzyl 5-deoxy-5-(N-diphenylphosphinoyl)amino-2,3-O-isopropylidene-β-D-ribofuranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 2524-64-3
chlorophosphoric acid diphenyl ester

: 328533-72-8
C-((3aR,4R,6R,6aR)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-methylamine

: 328533-47-7
benzyl 5-deoxy-5-(N-diphenylphosphinoyl)amino-2,3-O-isopropylidene-β-D-ribofuranoside

Guidance literature:: With triethylamine; In dichloromethane; at 20 ℃; for 21h;
DOI:10.1021/jo0057452

Reference yield:

: 23276-32-6
benzyl 2,3-O-isopropylidene-D-ribofuranoside

: 328533-47-7
benzyl 5-deoxy-5-(N-diphenylphosphinoyl)amino-2,3-O-isopropylidene-β-D-ribofuranoside

Guidance literature:: Multi-step reaction with 3 steps

1: 95 percent / ZnN₆*2Py; triphenylphosphine; diisopropyl azodicarboxylate / toluene / 63 h / 20 °C

2: tri-n-butylstannane; AIBN / benzene / 1.5 h / Heating

3: 93 percent / triethylamine / CH₂Cl₂ / 21 h / 20 °C

With Zn(N₃)2/bis-pyridine complex; 2,2'-azobis(isobutyronitrile); di-isopropyl azodicarboxylate; tri-n-butyl-tin hydride; triethylamine; triphenylphosphine; In dichloromethane; toluene; benzene;
DOI:10.1021/jo0057452

Reference yield:

: 98391-41-4
benzyl 5-azido-5-deoxy-2,3-O-isopropylidene-β-D-ribofuranoside

: 328533-47-7
benzyl 5-deoxy-5-(N-diphenylphosphinoyl)amino-2,3-O-isopropylidene-β-D-ribofuranoside

Guidance literature:: Multi-step reaction with 2 steps

1: tri-n-butylstannane; AIBN / benzene / 1.5 h / Heating

2: 93 percent / triethylamine / CH₂Cl₂ / 21 h / 20 °C

With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; triethylamine; In dichloromethane; benzene;
DOI:10.1021/jo0057452