2-Methyl(2.2)paracyclophane

Base Information

Chemical Name:2-Methyl(2.2)paracyclophane
CAS No.:24262-07-5
Molecular Formula:C17H18
Molecular Weight:222.3248
Hs Code.:
European Community (EC) Number:659-703-1
DSSTox Substance ID:DTXSID70178962
Nikkaji Number:J638.004B
Mol file:24262-07-5.mol

Synonyms:2-Methyl(2.2)paracyclophane;24262-07-5;2-Methyl[2.2]paracyclophane;4-methyl[2.2]paracyclophane;DTXSID70178962;AKOS024324614;5-methyltricyclo[8.2.2.2~4,7~]hexadeca-1(12),4,6,10,13,15-hexaene

Suppliers and Price of 2-Methyl(2.2)paracyclophane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of 2-Methyl(2.2)paracyclophane

Chemical Property:

Vapor Pressure:0.000196mmHg at 25°C
Boiling Point:338.1°Cat760mmHg
Flash Point:167.6°C
Density:1.02g/cm³
XLogP3:4.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:0
Exact Mass:222.140850574
Heavy Atom Count:17
Complexity:236

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=C2CCC3=CC=C(CCC(=C1)C=C2)C=C3

Technology Process of 2-Methyl(2.2)paracyclophane

There total 9 articles about 2-Methyl(2.2)paracyclophane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 1908-61-8,37503-79-0
4-bromo[2.2]paracyclophane

: 74-88-4
methyl iodide

: 24262-07-5,24351-81-3,33483-69-1
4-methyl<2.2>paracyclophane

Guidance literature:: 4-bromo[2.2]paracyclophane; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 1h; Inert atmosphere;

methyl iodide; In tetrahydrofuran; hexane; at -78 ℃; for 1h; Inert atmosphere;
DOI:10.1039/c3cc38769k

Reference yield:

: 36325-27-6,37044-38-5,729-30-6,147127-97-7
4-formyl[2.2]paracyclophane

: 24262-07-5,24351-81-3,33483-69-1
4-methyl<2.2>paracyclophane

Guidance literature:: With sodium hydroxide; hydrazine; diethylene glycol;
DOI:10.1021/ja00177a013

Reference yield:

: 1633-22-3
[2.2]Paracyclophan

: 24262-07-5,24351-81-3,33483-69-1
4-methyl<2.2>paracyclophane

Guidance literature:: Multi-step reaction with 4 steps

1: TiCl₄

2: LiAlH₄

3: PBr₃ / CH₂Cl₂

4: LiAlH₄ / tetrahydrofuran

With lithium aluminium tetrahydride; phosphorus tribromide; titanium tetrachloride; In tetrahydrofuran; dichloromethane;
DOI:10.1002/hlca.19810640704