(5R,6R)-5-(4-methylphenyl)-6-(phenylthio)-5,6,7,-8-tetrahydronaphtho[2,3-d]-1,3-dioxole

Base Information

Chemical Name:(5R,6R)-5-(4-methylphenyl)-6-(phenylthio)-5,6,7,-8-tetrahydronaphtho[2,3-d]-1,3-dioxole
CAS No.:1430205-69-8
Molecular Formula:C₂₄H₂₂O₂S
Molecular Weight:374.503
Hs Code.:

Synonyms:(5R,6R)-5-(4-methylphenyl)-6-(phenylthio)-5,6,7,-8-tetrahydronaphtho[2,3-d]-1,3-dioxole

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Chemical Property of (5R,6R)-5-(4-methylphenyl)-6-(phenylthio)-5,6,7,-8-tetrahydronaphtho[2,3-d]-1,3-dioxole

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Technology Process of (5R,6R)-5-(4-methylphenyl)-6-(phenylthio)-5,6,7,-8-tetrahydronaphtho[2,3-d]-1,3-dioxole

There total 3 articles about (5R,6R)-5-(4-methylphenyl)-6-(phenylthio)-5,6,7,-8-tetrahydronaphtho[2,3-d]-1,3-dioxole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 14204-27-4
N-phenylthiophthalimide

: 1430206-21-5
(E)-4-(3′,4′-methylenedioxyphenyl)-1-(4-methylphenyl)but-1-ene

: 1430205-69-8
(5R,6R)-5-(4-methylphenyl)-6-(phenylthio)-5,6,7,-8-tetrahydronaphtho[2,3-d]-1,3-dioxole

: (5S,6S)-5-(4-methylphenyl)-6-(phenylthio)-5,6,7,-8-tetrahydronaphtho[2,3-d]-1,3-dioxole

Guidance literature:: With ethanesulfonic acid; C₃₀H₃₆N₃PSe; In dichloromethane; at -20 ℃; for 48h; Overall yield = 86 %; Overall yield = 322 mg; enantioselective reaction; Inert atmosphere;
DOI:10.1021/ja401867b

Reference yield:

: 14204-27-4
N-phenylthiophthalimide

: C₁₈H₁₈O₂

: 1430205-69-8
(5R,6R)-5-(4-methylphenyl)-6-(phenylthio)-5,6,7,-8-tetrahydronaphtho[2,3-d]-1,3-dioxole

: 1567396-00-2
C₁₈H₁₈O₂

Guidance literature:: With methanesulfonic acid; (S)-4-(diisopropylamino)-3,5-dimethyl-4,5-dihydro-3H-dinaphtho[2,1-d:1’,2’-f][1,3,2]diazaphosphepine-4-selenide; In chloroform-d1; at -20 ℃; for 48h; Reagent/catalyst;
DOI:10.1021/ja413270h

Reference yield:

: 14204-27-4
N-phenylthiophthalimide

: C₁₈H₁₈O₂

: 1430205-69-8
(5R,6R)-5-(4-methylphenyl)-6-(phenylthio)-5,6,7,-8-tetrahydronaphtho[2,3-d]-1,3-dioxole

: (5S,6S)-5-(4-methylphenyl)-6-(phenylthio)-5,6,7,-8-tetrahydronaphtho[2,3-d]-1,3-dioxole

Guidance literature:: With methanesulfonic acid; (S)-4-(diisopropylamino)-3,5-dimethyl-4,5-dihydro-3H-dinaphtho[2,1-d:1’,2’-f][1,3,2]diazaphosphepine-4-selenide; In chloroform-d1; at -20 ℃; for 48h; Reagent/catalyst; Overall yield = 93 %; Overall yield = 42 mg; enantioselective reaction;
DOI:10.1021/ja413270h