12-<2-(4-diazo-1-oxocyclohexa-2,5-dienyl)methylenoxy>dodecanoic acid ethyl ester

Base Information

Chemical Name:12-<2-(4-diazo-1-oxocyclohexa-2,5-dienyl)methylenoxy>dodecanoic acid ethyl ester
CAS No.:173912-61-3
Molecular Formula:C₂₁H₃₂N₂O₄
Molecular Weight:376.496
Hs Code.:

Synonyms:12-<2-(4-diazo-1-oxocyclohexa-2,5-dienyl)methylenoxy>dodecanoic acid ethyl ester

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Chemical Property of 12-<2-(4-diazo-1-oxocyclohexa-2,5-dienyl)methylenoxy>dodecanoic acid ethyl ester

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Technology Process of 12-<2-(4-diazo-1-oxocyclohexa-2,5-dienyl)methylenoxy>dodecanoic acid ethyl ester

There total 4 articles about 12-<2-(4-diazo-1-oxocyclohexa-2,5-dienyl)methylenoxy>dodecanoic acid ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 942407-23-0
12-((2-hydroxy-5-aminobenzyl)oxy)dodecanoic acid ethyl ester

: 173912-61-3
12-<2-(4-diazo-1-oxocyclohexa-2,5-dienyl)methylenoxy>dodecanoic acid ethyl ester

Guidance literature:: With isopentyl nitrite; In acetic acid; at 10 ℃; for 1h;
DOI:10.1021/jo951350k

Reference yield:

: 505-95-3
12-hydroxydodecanoic acid

: 173912-61-3
12-<2-(4-diazo-1-oxocyclohexa-2,5-dienyl)methylenoxy>dodecanoic acid ethyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 99 percent / H₂SO₄ / 4 h / Heating

2: 85 percent / Ag₂O / CH₂Cl₂ / 48 h / Ambient temperature

3: 95 percent / NaBH₄ / Pd/C / tetrahydrofuran / 2 h / Ambient temperature

4: 65 percent / isoamyl nitrite / acetic acid / 1 h / 10 °C

With sodium tetrahydroborate; sulfuric acid; silver(l) oxide; isopentyl nitrite; palladium on activated charcoal; In tetrahydrofuran; dichloromethane; acetic acid;
DOI:10.1021/jo951350k

Reference yield:

: 78640-13-8
12-hydroxydodecanoic acid ethyl ester

: 173912-61-3
12-<2-(4-diazo-1-oxocyclohexa-2,5-dienyl)methylenoxy>dodecanoic acid ethyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 85 percent / Ag₂O / CH₂Cl₂ / 48 h / Ambient temperature

2: 95 percent / NaBH₄ / Pd/C / tetrahydrofuran / 2 h / Ambient temperature

3: 65 percent / isoamyl nitrite / acetic acid / 1 h / 10 °C

With sodium tetrahydroborate; silver(l) oxide; isopentyl nitrite; palladium on activated charcoal; In tetrahydrofuran; dichloromethane; acetic acid;
DOI:10.1021/jo951350k