O-(2-azido-2-deoxy-3,4,6-tri-O-benzyl-β-D-glucopyranosyl)-(1->6)-3,4-di-O-benzyl-D-galactal

Base Information

Chemical Name:O-(2-azido-2-deoxy-3,4,6-tri-O-benzyl-β-D-glucopyranosyl)-(1->6)-3,4-di-O-benzyl-D-galactal
CAS No.:944064-93-1
Molecular Formula:C₄₇H₄₉N₃O₈
Molecular Weight:783.921
Hs Code.:

Synonyms:O-(2-azido-2-deoxy-3,4,6-tri-O-benzyl-β-D-glucopyranosyl)-(1->6)-3,4-di-O-benzyl-D-galactal

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of O-(2-azido-2-deoxy-3,4,6-tri-O-benzyl-β-D-glucopyranosyl)-(1->6)-3,4-di-O-benzyl-D-galactal

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of O-(2-azido-2-deoxy-3,4,6-tri-O-benzyl-β-D-glucopyranosyl)-(1->6)-3,4-di-O-benzyl-D-galactal

There total 2 articles about O-(2-azido-2-deoxy-3,4,6-tri-O-benzyl-β-D-glucopyranosyl)-(1->6)-3,4-di-O-benzyl-D-galactal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

: 130323-37-4
(2R,3R,4R)-(3,4-bis(benzyloxy)-3,4-dihydro-2H-pyran-2-yl)methanol

: 220688-25-5
O-(2-azido-3,4,6-tri-O-benzyl-2-deoxy-α/β-D-glucopyranosyl) trichloroacetimidate

: 944064-93-1
O-(2-azido-2-deoxy-3,4,6-tri-O-benzyl-β-D-glucopyranosyl)-(1->6)-3,4-di-O-benzyl-D-galactal

Guidance literature:: tin (II) triflate; In acetonitrile; at -40 ℃; for 0.5h;
DOI:10.1021/jo061670b

Reference yield:

: 201800-34-2
3,4-di-O-benzyl-6-O-(tert-butyldiphenylsilyl)-D-galactal

: 944064-93-1
O-(2-azido-2-deoxy-3,4,6-tri-O-benzyl-β-D-glucopyranosyl)-(1->6)-3,4-di-O-benzyl-D-galactal

Guidance literature:: Multi-step reaction with 2 steps

1: 70 percent / tetrabutylammonium fluoride / tetrahydrofuran / 6 h

2: 58 percent / tin (II) triflate / acetonitrile / 0.5 h / -40 °C

With tetrabutyl ammonium fluoride; tin (II) triflate; In tetrahydrofuran; acetonitrile;
DOI:10.1021/jo061670b

Reference yield: 78.0%

: 944064-93-1
O-(2-azido-2-deoxy-3,4,6-tri-O-benzyl-β-D-glucopyranosyl)-(1->6)-3,4-di-O-benzyl-D-galactal

: 944064-94-2
O-(2-azido-2-deoxy-3,4,6-tri-O-benzyl-β-D-glucopyranosyl)-(1->6)-3,4-di-O-benzyl-2-deoxy-2-nitro-D-galactal

Guidance literature:: O-(2-azido-2-deoxy-3,4,6-tri-O-benzyl-β-D-glucopyranosyl)-(1->6)-3,4-di-O-benzyl-D-galactal; With nitric acid; acetic anhydride; In dichloromethane; at -30 ℃; for 1h;

With triethylamine; In dichloromethane; for 0.416667h; Further stages.;
DOI:10.1021/jo061670b