(CO)4Mo(μ-PPh2)(μ-H)Pt(PMe2Ph)2

Base Information

• Chemical Name: (CO)4Mo(μ-PPh2)(μ-H)Pt(PMe2Ph)2
• CAS No.: 123621-22-7
• Molecular Formula: C₃₂H₃₃MoO₄P₃Pt
• Molecular Weight: 865.553
• Mol file: 123621-22-7.mol

Synonyms:(CO)4Mo(μ-PPh2)(μ-H)Pt(PMe2Ph)2

Chemical Property of (CO)4Mo(μ-PPh2)(μ-H)Pt(PMe2Ph)2

Chemical Property:

Purity/Quality:

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Technology Process of (CO)4Mo(μ-PPh2)(μ-H)Pt(PMe2Ph)2

There total 3 articles about (CO)4Mo(μ-PPh2)(μ-H)Pt(PMe2Ph)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

trans-chlorobis(dimethylphenylphosphine)hydridoplatinum(II) (12112-64-0) + Mo(CO)4(PPh3)(PPh2H) (111611-59-7) → (CO)4Mo(μ-PPh2)(μ-H)Pt(PMe2Ph)2 (123621-22-7)

Guidance literature:

With LiCH₃; In tetrahydrofuran; diethyl ether; byproducts: P(C6H5)3, LiCl; under dry N2, LiCH3 in Et2O added to the Mo-complex in THF at 25°C, stirred for ca. 5 min, Pt-complex added,; volume reduced under vacuum; elem. anal., IR, NMR;

Reference yield: 40.0%

trans-chlorobis(dimethylphenylphosphine)hydridoplatinum(II) (12112-64-0) + Mo(CO)5(PPh2H) (18399-61-6) → (CO)4Mo(μ-PPh2)(μ-H)Pt(PMe2Ph)2 (123621-22-7)

Guidance literature:

With n-BuLi; In tetrahydrofuran; hexane; under dry N2, n-BuLi in hexane added to Mo-complex in THF at 22°C, stirred for a few min, Pt-complex added, solution allowed to stand for 20 h; filtered, washed (hexane), dried in vacuo; elem. anal., IR, NMR;

Reference yield:

trans-chlorobis(dimethylphenylphosphine)hydridoplatinum(II) (12112-64-0) + Li[(diphenylphosphide)Mo(CO)5] → (CO)4Mo(μ-PPh2)(μ-H)Pt(PMe2Ph)2 (123621-22-7)

Guidance literature:

In not given; under dry N2; elem. anal., IR, NMR;

upstream raw materials:

trans-chlorobis(dimethylphenylphosphine)hydridoplatinum(II)

Mo(CO)4(PPh₃)(PPh₂H)

Mo(CO)5(PPh2H)