trans-chlorobis(dimethylphenylphosphine)hydridoplatinum(II)

Base Information

• Chemical Name: trans-chlorobis(dimethylphenylphosphine)hydridoplatinum(II)
• CAS No.: 12112-64-0
• Molecular Formula: C₁₆H₂₃ClP₂Pt
• Molecular Weight: 507.839
• Mol file: 12112-64-0.mol

Synonyms:trans-chlorobis(dimethylphenylphosphine)hydridoplatinum(II)

Chemical Property of trans-chlorobis(dimethylphenylphosphine)hydridoplatinum(II)

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-chlorobis(dimethylphenylphosphine)hydridoplatinum(II)

There total 1 articles about trans-chlorobis(dimethylphenylphosphine)hydridoplatinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(butane-1,4-diyl)chlorobis(dimethylphenylphosphine)methylplatinum(IV) (59991-53-6) → trans-chlorobis(dimethylphenylphosphine)hydridoplatinum(II) (12112-64-0)

Guidance literature:

In neat (no solvent); byproducts: but-1-ene, methane, pent-1-ene; heating (10°C above m.p., in vac.); condensing volatile products in liquid-N2 cooled trap; IR and (1)H-NMR spectroscopy, gas chromy.; further byproduct: C6H6;

DOI:10.1039/DT9760000786

Reference yield: 65.0%

trans-chlorobis(dimethylphenylphosphine)hydridoplatinum(II) (12112-64-0) + triphenylgermane (2816-43-5) → trans-Pt(PMe2Ph)2(GePh3)Cl

Guidance literature:

In neat (no solvent); N2-atmosphere; stirring (90°C, 3 h); washing (Et2O, -20°C), drying (vac.);

DOI:10.1021/om970841n

Reference yield: 60.0%

trans-chlorobis(dimethylphenylphosphine)hydridoplatinum(II) (12112-64-0) + Mo(CO)4(PPh3)(PPh2H) (111611-59-7) → (CO)4Mo(μ-PPh2)(μ-H)Pt(PMe2Ph)2 (123621-22-7)

Guidance literature:

With LiCH₃; In tetrahydrofuran; diethyl ether; byproducts: P(C6H5)3, LiCl; under dry N2, LiCH3 in Et2O added to the Mo-complex in THF at 25°C, stirred for ca. 5 min, Pt-complex added,; volume reduced under vacuum; elem. anal., IR, NMR;

upstream raw materials:

(butane-1,4-diyl)chlorobis(dimethylphenylphosphine)methylplatinum(IV)

Downstream raw materials:

(CO)4Mo(μ-PPh2)(μ-H)Pt(PMe2Ph)2

(CO)4W(μ-PPh2)(μ-H)Pt(PMe2Ph)2

(CO)4Cr(μ-PPh2)(μ-H)Pt(PMe2Ph)2

trans-PtH{NC(CF₃)2}{P(CH₃)2C₆H₅}2