(p-methoxybenzyl)pentacarbonylmanganese(I)

Base Information

Chemical Name:(p-methoxybenzyl)pentacarbonylmanganese(I)
CAS No.:80105-78-8
Molecular Formula:C₁₃H₉MnO₆
Molecular Weight:316.149
Hs Code.:

Synonyms:(p-methoxybenzyl)pentacarbonylmanganese(I)

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Chemical Property of (p-methoxybenzyl)pentacarbonylmanganese(I)

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Technology Process of (p-methoxybenzyl)pentacarbonylmanganese(I)

There total 2 articles about (p-methoxybenzyl)pentacarbonylmanganese(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

: 13859-41-1
sodium pentacarbonyl manganate

: 824-94-2
p-methoxybenzyl chloride

: 80105-78-8
(p-methoxybenzyl)pentacarbonylmanganese(I)

Guidance literature:: In diethyl ether; byproducts: NaCl; react. of Na(Mn(CO)5) (from Mn2(CO)10 by Na/Hg redn.) with p-methoxybenzyl chloride at 0 °C., stirred at this temp. (5 h); addn. of hexane, filtration, partly evapd., crystals washed (cold hexane), air-dried; remaing filtrate chromd. (silica gel, hexane);
DOI:10.1021/om00113a012

Reference yield: 53.0%

: 10170-69-1
dimanganese decacarbonyl

: 824-94-2
p-methoxybenzyl chloride

: 80105-78-8
(p-methoxybenzyl)pentacarbonylmanganese(I)

Guidance literature:: With sodium amalgam; In tetrahydrofuran; Mn2(CO)10 was reacted for 2 h at room temp. with Na#Hg in THF; p-CH3OC6H4CH2Cl soln. was added dropwise; stirred overnight, filtered, THF removed by high vac.; dissolved in pentane, filtered; reduced in vol., cooled to -20°C for 24 h; cooled to -78°C, filtered and washed with cold pentane at -78°C;
DOI:10.1021/om00120a007

Reference yield: 80.0%

: 80105-78-8
(p-methoxybenzyl)pentacarbonylmanganese(I)

: 104419-63-8,61477-64-3
HMn(CO)4(P(CH₃)2C₆H₅)

: 5703-26-4
4-Methoxyphenylacetaldehyde

: 50540-29-9
nonacarbonyl(dimethylphenylphosphine)dimanganese

Guidance literature:: With carbon monoxide; Triphenylphosphine oxide; In benzene-d6; High Pressure; in C6D6 at 45°C, initial concn. ranges were 3.8E-3 to 2.4E-2 M p-MeOC6H4CH2Mn(CO)5, 3.3E-2 to 0.16 M HMn(CO)4(PMe2Ph) (typically 10-fold excess), 0.040 to 0.30 M OPPh3, and 1.1 to 2.3 atm (8.1E-3 to 1.7E-2 M) of CO; followed by NMR and FTIR; Kinetics;
DOI:10.1021/ja00262a054