Acetic acid (3aR,4R,6R,6aS)-6-benzyloxyamino-2,2-dimethyl-tetrahydro-cyclopenta[1,3]dioxol-4-yl ester

Base Information

Chemical Name:Acetic acid (3aR,4R,6R,6aS)-6-benzyloxyamino-2,2-dimethyl-tetrahydro-cyclopenta[1,3]dioxol-4-yl ester
CAS No.:138946-57-3
Molecular Formula:C₁₇H₂₃NO₅
Molecular Weight:321.373
Hs Code.:

Synonyms:Acetic acid (3aR,4R,6R,6aS)-6-benzyloxyamino-2,2-dimethyl-tetrahydro-cyclopenta[1,3]dioxol-4-yl ester

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Chemical Property of Acetic acid (3aR,4R,6R,6aS)-6-benzyloxyamino-2,2-dimethyl-tetrahydro-cyclopenta[1,3]dioxol-4-yl ester

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Technology Process of Acetic acid (3aR,4R,6R,6aS)-6-benzyloxyamino-2,2-dimethyl-tetrahydro-cyclopenta[1,3]dioxol-4-yl ester

There total 4 articles about Acetic acid (3aR,4R,6R,6aS)-6-benzyloxyamino-2,2-dimethyl-tetrahydro-cyclopenta[1,3]dioxol-4-yl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 138946-49-3,138946-50-6
Acetic acid (S)-1-[(4S,5S)-5-(benzyloxyimino-methyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-2-bromo-ethyl ester

: 138946-57-3
Acetic acid (3aR,4R,6R,6aS)-6-benzyloxyamino-2,2-dimethyl-tetrahydro-cyclopenta[1,3]dioxol-4-yl ester

Guidance literature:: With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In benzene; at 80 ℃;
DOI:10.1039/c39940000083

Reference yield:

: 2687-43-6
O-benzylhydoxylamine hydrochloride

: 138946-57-3
Acetic acid (3aR,4R,6R,6aS)-6-benzyloxyamino-2,2-dimethyl-tetrahydro-cyclopenta[1,3]dioxol-4-yl ester

Guidance literature:: Multi-step reaction with 3 steps

1: pyridine / CH₂Cl₂ / Heating

2: pyridine / Ambient temperature

3: 52 percent / tributyltin hydride, AIBN / benzene / 1) 5 h; 2) reflux, 10 h

With pyridine; 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In dichloromethane; benzene;
DOI:10.1021/jo970987w

Reference yield:

: 138946-44-8
(3R,4S,5S)-5-(bromomethyl)-3,4-O-isopropylidenetetrahydrofuran-2,3,4-triol

: 138946-57-3
Acetic acid (3aR,4R,6R,6aS)-6-benzyloxyamino-2,2-dimethyl-tetrahydro-cyclopenta[1,3]dioxol-4-yl ester

Guidance literature:: Multi-step reaction with 3 steps

1: pyridine / CH₂Cl₂ / Heating

2: pyridine / Ambient temperature

3: 52 percent / tributyltin hydride, AIBN / benzene / 1) 5 h; 2) reflux, 10 h

With pyridine; 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In dichloromethane; benzene;
DOI:10.1021/jo970987w