[Au₄((p-tolyl)NCHN(p-tolyl)4]

Base Information

Chemical Name:[Au₄((p-tolyl)NCHN(p-tolyl)4]
CAS No.:705950-30-7
Molecular Formula:C₆₀H₆₀Au₄N₈
Molecular Weight:1681.06
Hs Code.:

[Au<sub>4</sub>((p-tolyl)NCHN(p-tolyl)4]

Synonyms:[Au₄((p-tolyl)NCHN(p-tolyl)4]

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Chemical Property of [Au₄((p-tolyl)NCHN(p-tolyl)4]

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Technology Process of [Au₄((p-tolyl)NCHN(p-tolyl)4]

There total 1 articles about [Au₄((p-tolyl)NCHN(p-tolyl)4] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 15.0%

: 839679-31-1,957934-09-7
Au₂(N,N'-bis(2,6-dimethylphenyl)formamidinate)2

: 16596-03-5,141417-88-1
N,N'-di-p-tolylformamidine

: 705950-30-7
[Au₄((p-tolyl)NCHN(p-tolyl)4]

Guidance literature:: With KOH; In tetrahydrofuran; byproducts: K(N,N'-bis(2,6-dimethylphenylformamidine; formamidine was stirred with KOH in THF for 24 h, Au-complex was added, the mixt. was stirred for 24 h; the solvent was removed under vac.; dissolved in CH2Cl2, K-salt was extd. with water-ethanol (1:1), recrystd. from THF/hexane;
DOI:10.1021/ic0612449

Reference yield:

: 705950-30-7
[Au₄((p-tolyl)NCHN(p-tolyl)4]

: 7440-57-5,457905-15-6
gold

Guidance literature:: In neat (no solvent); Au complex dissolved in THF; deposited onto MgO support at 300 K; MgO support was annealed to 900-1300 K prior to deposition of the Au; deposited Au complex treated in flowing O2 at 773 K for 3 h;
DOI:10.1021/ja043652m