trans-(+/-)-<(2-Methyl-3-cyclohexen-1-yl)oxy>(1,1-dimethylethyl)dimethylsilane

Base Information

Chemical Name:trans-(+/-)-<(2-Methyl-3-cyclohexen-1-yl)oxy>(1,1-dimethylethyl)dimethylsilane
CAS No.:115802-77-2
Molecular Formula:C₁₃H₂₆OSi
Molecular Weight:226.434
Hs Code.:

Synonyms:trans-(+/-)-<(2-Methyl-3-cyclohexen-1-yl)oxy>(1,1-dimethylethyl)dimethylsilane

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Chemical Property of trans-(+/-)-<(2-Methyl-3-cyclohexen-1-yl)oxy>(1,1-dimethylethyl)dimethylsilane

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Technology Process of trans-(+/-)-<(2-Methyl-3-cyclohexen-1-yl)oxy>(1,1-dimethylethyl)dimethylsilane

There total 2 articles about trans-(+/-)-<(2-Methyl-3-cyclohexen-1-yl)oxy>(1,1-dimethylethyl)dimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 64698-20-0,81452-69-9,81452-74-6,135840-34-5
(rac)-trans-2-Methylcyclohex-3-en-1-ol

: 18162-48-6
tert-butyldimethylsilyl chloride

: 115802-77-2
trans-(+/-)-<(2-Methyl-3-cyclohexen-1-yl)oxy>(1,1-dimethylethyl)dimethylsilane

Guidance literature:: With 1H-imidazole; dmap; In N,N-dimethyl-formamide; Ambient temperature;
DOI:10.1016/S0040-4020(01)86450-4

Reference yield:

: 6705-51-7
3,4-epoxycyclohexene

: 115802-77-2
trans-(+/-)-<(2-Methyl-3-cyclohexen-1-yl)oxy>(1,1-dimethylethyl)dimethylsilane

Guidance literature:: Multi-step reaction with 2 steps

1: 83 percent / diethyl ether

2: 90 percent / 4-N,N-dimethylaminopyridine / dimethylformamide

With dmap; In diethyl ether; N,N-dimethyl-formamide;
DOI:10.1039/c39880000217

Reference yield:

: 115802-77-2
trans-(+/-)-<(2-Methyl-3-cyclohexen-1-yl)oxy>(1,1-dimethylethyl)dimethylsilane

: 115802-81-8
Methyl -(+/-)-5-<<(1,1-dimethylethyl)dimethylsilyl>oxy>-2,4-dimethyl-7-oxo-8-(phenylmethoxy)-2-octenoate

Guidance literature:: Multi-step reaction with 6 steps

1: 1.) O₃, 2.) H₂ / 2.) Pd/C / 2.) MeOH

2: dibenzylammonium trifluoroacetate / CH₂Cl₂

3: 95 percent / Li(O-t-Bu)3H

4: 90 percent / NaH, NaI / 1,2-dimethoxy-ethane

5: 1.) O₃, 2.) triphenylphosphine

6: 55 percent

With hydrogen; sodium hydride; ozone; lithium tri-t-butoxyaluminum hydride; triphenylphosphine; sodium iodide; dibenzylammonium trifluoroacetate salt; palladium on activated charcoal; In 1,2-dimethoxyethane; dichloromethane;
DOI:10.1039/c39880000217