5''-{4-[9-(4-Methoxy-phenyl)-[1,10]phenanthrolin-2-yl]-butyl}-5-(3-{4-[tris-(4-tert-butyl-phenyl)-methyl]-phenoxy}-propyl)-[2,2';6',2'']terpyridine

Base Information

• Chemical Name: 5''-{4-[9-(4-Methoxy-phenyl)-[1,10]phenanthrolin-2-yl]-butyl}-5-(3-{4-[tris-(4-tert-butyl-phenyl)-methyl]-phenoxy}-propyl)-[2,2';6',2'']terpyridine
• CAS No.: 190366-45-1
• Molecular Formula: C₇₈H₇₉N₅O₂
• Molecular Weight: 1118.52
• Mol file: 190366-45-1.mol

Synonyms:5''-{4-[9-(4-Methoxy-phenyl)-[1,10]phenanthrolin-2-yl]-butyl}-5-(3-{4-[tris-(4-tert-butyl-phenyl)-methyl]-phenoxy}-propyl)-[2,2';6',2'']terpyridine

Chemical Property of 5''-{4-[9-(4-Methoxy-phenyl)-[1,10]phenanthrolin-2-yl]-butyl}-5-(3-{4-[tris-(4-tert-butyl-phenyl)-methyl]-phenoxy}-propyl)-[2,2';6',2'']terpyridine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5''-{4-[9-(4-Methoxy-phenyl)-[1,10]phenanthrolin-2-yl]-butyl}-5-(3-{4-[tris-(4-tert-butyl-phenyl)-methyl]-phenoxy}-propyl)-[2,2';6',2'']terpyridine

There total 7 articles about 5''-{4-[9-(4-Methoxy-phenyl)-[1,10]phenanthrolin-2-yl]-butyl}-5-(3-{4-[tris-(4-tert-butyl-phenyl)-methyl]-phenoxy}-propyl)-[2,2';6',2'']terpyridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

2-methyl-9-(p-anisyl)-1,10-phenanthroline (142942-22-1) + 5''-(3-Bromo-propyl)-5-(3-{4-[tris-(4-tert-butyl-phenyl)-methyl]-phenoxy}-propyl)-[2,2';6',2'']terpyridine (190366-44-0) → 5''-{4-[9-(4-Methoxy-phenyl)-[1,10]phenanthrolin-2-yl]-butyl}-5-(3-{4-[tris-(4-tert-butyl-phenyl)-methyl]-phenoxy}-propyl)-[2,2';6',2'']terpyridine (190366-45-1)

Guidance literature:

With lithium diisopropyl amide; In tetrahydrofuran; Ambient temperature;

DOI:10.1016/S0040-4039(97)00678-3

Reference yield:

5,5''-dimethyl-2,2':6',2''-terpyridine (158589-14-1) → 5''-{4-[9-(4-Methoxy-phenyl)-[1,10]phenanthrolin-2-yl]-butyl}-5-(3-{4-[tris-(4-tert-butyl-phenyl)-methyl]-phenoxy}-propyl)-[2,2';6',2'']terpyridine (190366-45-1)

Guidance literature:

Multi-step reaction with 6 steps

1: 1.) LDA / 1.) THF, a) -78 deg C, 2 h, b) 0 deg C, 0.5 h, 2.) THF, from 0 deg C to RT, 16 h

2: 96 percent / aq. HCl, EtOH / 3 h / Heating

3: 90 percent / Et₃N / CH₂Cl₂ / 4 h / -2 °C

4: 13 percent / K₂CO₃ / dimethylformamide / 18 h / 75 °C

5: 80 percent / LiBr / acetone / 2 h / Heating

6: 1.) LDA / 1.) THF, a) -78 deg C, 2 h, 2.) from -78 deg C to 0 deg C, 1 h, 2.) THF, from 0 deg C to RT, 16 h

With hydrogenchloride; ethanol; potassium carbonate; triethylamine; lithium bromide; lithium diisopropyl amide; In dichloromethane; N,N-dimethyl-formamide; acetone;

DOI:10.1021/ja984051w

Reference yield:

5,5''-bis-(3-methanesulfonyl-1-propyl)-2,2':6',2''-terpyridine (158589-18-5) → 5''-{4-[9-(4-Methoxy-phenyl)-[1,10]phenanthrolin-2-yl]-butyl}-5-(3-{4-[tris-(4-tert-butyl-phenyl)-methyl]-phenoxy}-propyl)-[2,2';6',2'']terpyridine (190366-45-1)

Guidance literature:

Multi-step reaction with 3 steps

1: 13 percent / K₂CO₃ / dimethylformamide / 18 h / 75 °C

2: 80 percent / LiBr / acetone / 2 h / Heating

3: 1.) LDA / 1.) THF, a) -78 deg C, 2 h, 2.) from -78 deg C to 0 deg C, 1 h, 2.) THF, from 0 deg C to RT, 16 h

With potassium carbonate; lithium bromide; lithium diisopropyl amide; In N,N-dimethyl-formamide; acetone;

DOI:10.1021/ja984051w

upstream raw materials:

2-methyl-9-(p-anisyl)-1,10-phenanthroline

5''-(3-Bromo-propyl)-5-(3-{4-[tris-(4-tert-butyl-phenyl)-methyl]-phenoxy}-propyl)-[2,2';6',2'']terpyridine

5,5''-dimethyl-2,2':6',2''-terpyridine

5,5''-bis-(3-hydroxy-1-propyl)-2,2':6',2''-terpyridine

Downstream raw materials:

((C₄H₉C₆H₄)3CC₆H₄O(CH₂)3(C₅H₃N)3(CH₂)4(C₁₂H₆N₂)C₆H₄OCH₃)Cu(C₁₂H₆N₂(C₆H₄)2O(CH₂CH₂O)5)⁽¹⁺⁾*PF₆^(1-)=[C₁₁₂H₁₁₃N₇O₈Cu][PF₆]