Sodium cacodylate

Base Information

• Chemical Name: Sodium cacodylate
• CAS No.: 124-65-2
• Deprecated CAS: 63665-22-5
• Molecular Formula: C2H7AsO2.Na
• Molecular Weight: 159.98
• Hs Code.: 2931900022
• European Community (EC) Number: 204-708-2
• UN Number: 1688
• UNII: OC4237N148
• DSSTox Substance ID: DTXSID3034408
• Nikkaji Number: J297.788E
• Wikipedia: Sodium salt of cacodylic acid
• Wikidata: Q26840782
• NCI Thesaurus Code: C84150
• ChEMBL ID: CHEMBL2079844
• Mol file: 124-65-2.mol

Synonyms:SODIUM CACODYLATE;Sodium dimethylarsinate;124-65-2;Arsicodile;Alkarsodyl;Cacodylic acid sodium salt;Dimethylarsinic acid sodium salt;Arsecodile;Arsycodile;Arsysodila;Chemaid;Bolate;Bophy;Dutch-treat;Sodium dimethylarsonate;Bolls-eye;Sodium dimethyl arsinate;Rad-E-Cate;Cacodylate de sodium;Sodium salt of cacodylic acid;((Dimethylarsino)oxy)sodium As-oxide;((Dimethylarsino)oxy)sodium-As-oxide;Caswell No. 133A;Rad-E-Cate 16;Rad-E-Cate 25;Kakodylan dodny;Kakodylan dodny [Czech];Dimethylarsinat sodny [Czech];Dimethylarsinat sodny;Cacodylate de sodium [French];Hydroxydimethylarsine oxide, sodium salt;CCRIS 7929;HSDB 731;Sodium cacodylate [NF];NSC 1910;EINECS 204-708-2;UN1688;Arsinic acid, dimethyl-, sodium salt;Sodium Cacodylate [USAN];EPA Pesticide Chemical Code 012502;Sodium, ((dimethylarsino)oxy)-, As-oxide;Arsine oxide, hydroxydimethyl-, sodium salt;1246522-05-3;UNII-OC4237N148;CHEBI:62956;OC4237N148;Arsine oxide, dimethylhydroxy-, sodium salt;Sodium dimethylarsinate (0.1M buffer soln., pH 7.0);[(Dimethylarsino)oxy]sodium As-oxide;NSC-1910;Dimethylarsenic acid sodium salt trihydrate;Broadsides;sodium;dimethylarsinate;sodium dimethyl arsonide;SCD (CHRIS Code);C2H7AsO2.Na;CACODYLATE, SODIUM;C2-H7-As-O2.Na;SCHEMBL43010;SODIUM CACODYLATE [MI];CHEMBL2079844;DTXSID3034408;SODIUM CACODYLATE [HSDB];IHQKEDIOMGYHEB-UHFFFAOYSA-M;SODIUM CACODYLATE [MART.];SODIUM CACODYLATE [WHO-DD];ARSINATE, DIMETHYL-, SODIUM;NA1688;AKOS016010300;Sodium cacodylate [UN1688] [Poison];Sodium cacodylate [UN1688] [Poison];LS-21868;LS-21870;Sodium cacodylate;(Sodium dimethylarsinate);Q26840782

Chemical Property of Sodium cacodylate

Chemical Property:

• Appearance/Colour: white crystals or powder
• Melting Point: 60oC
• Boiling Point: 253.1 °C at 760 mmHg
• Flash Point: 109.4 °C
• PSA: 40.13000
• LogP: 0.54920
• Storage Temp.: Store at RT.
• Solubility.: H2O: 0.5 M at 20 °C, clear, colorless
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 159.948143
• Heavy Atom Count: 6
• Complexity: 65.9
• Transport DOT Label: Poison

Purity/Quality:

99%, ^*data from raw suppliers

CACODYLICACIDSODIUMSALT 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T; N
• Hazard Codes: T,N
• Statements: 23/25-50/53
• Safety Statements: 20/21-28-45-60-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Metals -> Arsenic Compounds, Organic
• Canonical SMILES: C[As](=O)(C)[O-].[Na+]
• Uses: Herbicide.

Technology Process of Sodium cacodylate

There total 1 articles about Sodium cacodylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methylarsine oxide (593-58-8) + methyl iodide (74-88-4) → sodium cacodylate (124-65-2)

Guidance literature:

With methanol; sodium hydroxide;

Reference yield: 74.0%

sodium cacodylate (124-65-2) + μ-oxo-bis[bromotriphenylantimony(V)] (1538-64-3) → [(Sb(C6H5)3)2(O)(O2As(CH3)2)2] (196503-09-0)

Guidance literature:

In dichloromethane; reflux (20 h); filtration, removal of solvent (vac.), dissoln. (CHCl3), diffusion of hexane into the soln.; elem. anal.;

DOI:10.1039/a702244a

Reference yield: 54.0%

sodium cacodylate (124-65-2) → dimethyliodoarsine (676-75-5)

Guidance literature:

With hydrogenchloride; sulfur dioxide; potassium iodide; In water; for 2h;

DOI:10.1016/j.tetlet.2016.12.040

upstream raw materials:

methylarsine oxide

methyl iodide

Downstream raw materials:

dimethylarsine

tetramethyldiarsine

Darinaparsin

[(Sb(C₆H₅)3)2(O)(O₂As(CH₃)2)2]