Thiophosphoric acid O,O'-dimethyl ester O''-((2R,3S,4S,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl) ester

Base Information

Chemical Name:Thiophosphoric acid O,O'-dimethyl ester O''-((2R,3S,4S,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl) ester
CAS No.:212119-72-7
Molecular Formula:C₃₆H₄₁O₈PS
Molecular Weight:664.756
Hs Code.:

Synonyms:Thiophosphoric acid O,O'-dimethyl ester O''-((2R,3S,4S,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl) ester

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Chemical Property of Thiophosphoric acid O,O'-dimethyl ester O''-((2R,3S,4S,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl) ester

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Technology Process of Thiophosphoric acid O,O'-dimethyl ester O''-((2R,3S,4S,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl) ester

There total 1 articles about Thiophosphoric acid O,O'-dimethyl ester O''-((2R,3S,4S,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl) ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 4132-28-9,4291-69-4,6386-24-9,6564-72-3,59531-24-7,69257-52-9,78184-89-1,78609-16-2,78609-17-3,78609-18-4,96553-53-6,104111-61-7,131347-08-5
2,3,4,6-tetra-O-benzyl-D-mannopyranose

: 2524-03-0
dimethyl chlorothiophosphate

: 212119-72-7
Thiophosphoric acid O,O'-dimethyl ester O''-((2R,3S,4S,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl) ester

Guidance literature:: With n-butyllithium; Yield given. Multistep reaction; 1.) THF, hexane, -30 deg C, 1 h, 2.) -30 deg C -> rt;
DOI:10.1080/07328309808002336

Reference yield: 78.0%

: 19488-48-3
methyl O-2,3,6-tri-O-benzyl-α-D-glucopyranoside

: 212119-72-7
Thiophosphoric acid O,O'-dimethyl ester O''-((2R,3S,4S,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl) ester

: 64694-18-4,77117-44-3,81307-79-1,82805-15-0,82805-16-1,82805-17-2,82805-18-3,84799-76-8,114817-97-9,114817-98-0,117894-99-2,123806-51-9,123877-32-7,117894-98-1
methyl 4-O-(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)(1→4)-2,3,6-tri-O-benzyl-α-D-glucopyranoside

Guidance literature:: With 4 Angstroem MS; silver trifluoromethanesulfonate; In dichloromethane; toluene; at -78 - 20 ℃;
DOI:10.1080/07328309808002336

Reference yield:

: 212119-72-7
Thiophosphoric acid O,O'-dimethyl ester O''-((2R,3S,4S,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl) ester

: 4064-06-6
1,2:3,4-di-O-isopropylidene-α-D-galactopyranose

: 117841-67-5
6-O-(2,3,4,6-tetra-O-benzyl-β-D-mannopyranosyl)-(1->6)-1,2:3,4-di-O-isopropylidene-α-D-galactopyranoside

: 117841-66-4
6-O-(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)-(1->6)-1,2:3,4-di-O-isopropylidene-α-D-galactopyranoside

Guidance literature:: With 4 Angstroem MS; silver trifluoromethanesulfonate; In dichloromethane; toluene; at -78 - 20 ℃; Yield given. Yields of byproduct given;
DOI:10.1080/07328309808002336