(1R,6S,7S)-7-formyl-2,2,6-trimethylbicyclo[4.2.0]octan-7-yl pentafluorobenzoate

Base Information

Chemical Name:(1R,6S,7S)-7-formyl-2,2,6-trimethylbicyclo[4.2.0]octan-7-yl pentafluorobenzoate
CAS No.:947685-88-3
Molecular Formula:C₁₉H₁₉F₅O₃
Molecular Weight:390.35
Hs Code.:

Synonyms:(1R,6S,7S)-7-formyl-2,2,6-trimethylbicyclo[4.2.0]octan-7-yl pentafluorobenzoate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1R,6S,7S)-7-formyl-2,2,6-trimethylbicyclo[4.2.0]octan-7-yl pentafluorobenzoate

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Technology Process of (1R,6S,7S)-7-formyl-2,2,6-trimethylbicyclo[4.2.0]octan-7-yl pentafluorobenzoate

There total 2 articles about (1R,6S,7S)-7-formyl-2,2,6-trimethylbicyclo[4.2.0]octan-7-yl pentafluorobenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 849405-73-8
3,3-dimethylcyclohex-1-en-1-yl trifluoromethanesulfonate

: 947685-88-3
(1R,6S,7S)-7-formyl-2,2,6-trimethylbicyclo[4.2.0]octan-7-yl pentafluorobenzoate

Guidance literature:: Multi-step reaction with 2 steps

1: 75 percent / Fe(acac)3 / tetrahydrofuran; diethyl ether; 1-methyl-pyrrolidin-2-one / 1 h / -30 °C

2: H-L-Phe-L-Leu-N(CH₂CH₂)2-reduced triamine*HNTf₂ / various solvent(s) / 72 h / -20 °C

With H-L-Phe-L-Leu-N(CH₂CH₂)2-reduced triamine*HNTf₂; iron(III)-acetylacetonate; In tetrahydrofuran; 1-methyl-pyrrolidin-2-one; diethyl ether;
DOI:10.1021/ja073435w

Reference yield:

: α-(pentafluorobenzoyloxy)acrolein

: 503-47-9
1,3,3-trimethyl-1-cyclohexene

: 947685-88-3
(1R,6S,7S)-7-formyl-2,2,6-trimethylbicyclo[4.2.0]octan-7-yl pentafluorobenzoate

: C₁₉H₁₉O₃F₅

: (1SR,6SR,7SR)-7-formyl-2,2,6-trimethylbicyclo[4.2.0]octan-7-yl pentafluorobenzoate

Guidance literature:: With H-L-Phe-L-Leu-N(CH₂CH₂)2-reduced triamine*HNTf₂; In various solvent(s); at -20 ℃; for 72h; Title compound not separated from byproducts.;
DOI:10.1021/ja073435w