503-47-9

Usage

Uses

Used in Pharmaceutical Industry:
1,3,3-Trimethylcyclohexene is used as a starting material for the synthesis of pharmaceuticals, contributing to the development of new drugs and medicinal compounds.
Used in Fragrance Industry:
1,3,3-Trimethylcyclohexene is used as a starting material for the synthesis of fragrances, providing unique scents and enhancing the sensory experience of various products.
Used in Polymer Industry:
1,3,3-Trimethylcyclohexene is used as a starting material for the synthesis of polymers, contributing to the development of new materials with specific properties and applications.
Used in Organic Chemistry Research:
1,3,3-Trimethylcyclohexene is used as a research compound in organic chemistry, aiding in the exploration of chemical reactions, mechanisms, and the discovery of new synthetic pathways.
Used as a Laboratory Solvent:
1,3,3-Trimethylcyclohexene is used as a solvent in laboratory settings, facilitating various chemical reactions and processes.
Safety Precautions:
Individuals handling 1,3,3-trimethylcyclohexene should take proper safety precautions to avoid potential hazards due to its flammable nature.

InChI:InChI=1/C9H16/c1-8-5-4-6-9(2,3)7-8/h7H,4-6H2,1-3H3

Upstream product

• 4573-05-1 1,3-dimethyl-1,3-cyclohexadiene 
• 75-16-1 methylmagnesium bromide 
• 29481-98-9 1,3-dimethyl-2-cyclohexen-1-ol 
• 49815-62-5 4-(2',6',6'-trimethyl-2'-cyclohexenyl)-1,6-heptadien-4-ol 
• 78672-65-8 (2,2,6-Trimethyl-cyclohexylidene)-methanone 
• 6709-39-3 2,6-dimethyl-hepta-1,5-diene 
• 79802-79-2 1,3,3-trimethyl-cyclohexan-1-ol 
• 849405-73-8 3,3-dimethylcyclohex-1-en-1-yl trifluoromethanesulfonate 
• 37779-25-2 1,5,5-trimethylcyclohex-2-ene-1-ol 
• 28043-10-9 methyl 2,6,6-trimethyl-cyclohex-2-en-1-yl carboxylate 
• 78737-55-0 2,2,6-Trimethyl-cyclohexanecarbonyl chloride 
• 1193-18-6 3-methylcyclohexen-2-one 
• 41780-73-8 2,2,6-trimethylcyclohexanone tosylhydrazone 

Downstream Products

• 73466-63-4 C₁₅H₂₂O₄ 
• 73466-66-7 2-(2,2-dimethyl-1,3-dioxolan-4-on-5-yl)-2,6,6-trimethylcyclohexanecarboxylic acid 
• 947685-88-3 (1R,6S,7S)-7-formyl-2,2,6-trimethylbicyclo[4.2.0]octan-7-yl pentafluorobenzoate 
• 31191-93-2 2-methylene-6,6-dimethyl-1-[but-2-enoyl]-cyclohexane 
• 24720-09-0 α-damascone 
• 104446-40-4 (3AR,7AS)-2-oxo-3-phenylselenyl-4,4,7a-trimethyloctahydrobenzofuran 
• 35076-50-7 γ-damascol 
• 117750-13-7 C₉H₁₅⁽²⁾H 
• 100395-83-3 1,1,3-trimethyl-3-propyl-cyclohexane 
• 102943-76-0 1-ethyl-1,3,3-trimethyl-cyclohexane 
• 106038-48-6 1,1,3-Trimethyl-3-butyl-cyclohexan 
• 3073-66-3 1,1,3-trimethylcyclohexane 

Relevant academic research and scientific papers

Total synthesis of (±)-dihydroactinidiolide using selenium-stabilized carbenium ion

A new, short total synthesis of dihydroactinidiolide 1 is described using selenium carbenium ion-promoted carbon-carbon bond formation as the key step. Our synthetic strategy starts with a lactonization reaction between 1,3,3-trimethylcyclohexene 13 and α-chloro-α-phenylseleno ethyl acetate 14, affording the key intermediate, α-phenylseleno-γ-butyro lactone 15, which reacted via a selenoxide elimination to the target compound 1.

Enantioselective [2 + 2] cycloaddition of unactivated alkenes with α-acyloxyacroleins catalyzed by chiral organoammonium salts

We report the first example of an organocatalytic enantioselective [2 + 2] cycloaddition reaction of unactivated alkenes with α-acyloxyacroleins to give optically active 1-acyloxycyclobutanecarbaldehydes and subsequent ring expansion to give optically active 2-hydroxycyclopentanone derivatives. Organoammonium salt, H-L-Phe-L-Leu-N(CH2CH2)2-reduced triamine?2.6HNTf2, is a highly effective chiral catalyst for the above enantioselective [2 + 2] cycloaddition. Thus, we have developed a novel and useful formal enantioselective [2 + 3] cycloaddition through two steps. Copyright

Facile synthesis of isodamascone and its analogs

Synthesis of isodamascone and its analogs, the commercially important aroma compounds, have been accomplished from the readily available 1,5,5-trimethyl-2-cyclohexen-1-ol via a short, facile, and simple sequence of reactions in excellent yield. Copyright Taylor & Francis Group, LLC.

172. β-Cleavage of Bis(homoallylic) Potassium Alkoxides. Two-Step Preparation of Propenyl Ketones from Carboxylic Esters. Synthesis of ar-Turmerone, α-Damascone, β-Damascone, and β-Damascenone

The transformation of 36 bis(homoallylic) alcohols VII to alkenones IX and X via β-cleavage of their potassium alkoxides VIIa in HMPA has been investigated (cf.Scheme 2).These studies have established an order of β-cleavage for 2-propenyl, 1-methyl-2-propenyl, 2-methyl-2-propenyl, 1,1-dimethyl-2-propenyl, and benzyl groups in alkoxides 49a-56a and have allowed a comparison between the β-cleavage reaction and the oxy-Cope rearrangement in alkoxides 74a-83a.As illustrative synthetic applications, a two-step preparation of propenyl ketones 15-42 from carboxylic esters is described, together with syntheses of ar-turmerone (48), α-damascone ((E)-71), β-damascone ((E)-109), and β-damascenone ((E)-111).

SYNTHESIS WITH ORGANOBORANES. 2. SYNTHESIS OF α- AND γ-DAMASCONE

Selective synthesis of α- and γ-damascone, using allylic organoboranes as key intermediates, are described.