Technology Process of ethyl 2,3,3-tri(4-benzyloxy-3-methoxyphenyl)prop-2-enoate
There total 10 articles about ethyl 2,3,3-tri(4-benzyloxy-3-methoxyphenyl)prop-2-enoate which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; tris-(dibenzylideneacetone)dipalladium(0); triethylamine;
In
water;
at 60 ℃;
for 15h;
Reagent/catalyst;
Temperature;
Catalytic behavior;
Inert atmosphere;
DOI:10.1016/j.bmc.2017.01.050
- Guidance literature:
-
With
tetrakis(triphenylphosphine) palladium(0); potassium acetate;
In
N,N-dimethyl-formamide;
at 110 ℃;
for 2h;
Schlenk technique;
Inert atmosphere;
DOI:10.1002/ejoc.201901830
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: potassium carbonate / acetone / 0.08 h / Inert atmosphere
1.2: Inert atmosphere; Reflux
2.1: Dess-Martin periodane / dichloromethane / 2 h / 0 - 20 °C / Inert atmosphere
3.1: triphenylphosphine; carbon tetrabromide / dichloromethane / 12 h / 20 °C / Inert atmosphere
4.1: tris-(dibenzylideneacetone)dipalladium(0); potassium phosphate; dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane / toluene / 12 h / 110 °C / Inert atmosphere
With
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0); carbon tetrabromide; potassium carbonate; Dess-Martin periodane; triphenylphosphine;
In
dichloromethane; acetone; toluene;
4.1: |Suzuki-Miyaura Coupling;
DOI:10.1016/j.tetlet.2013.07.048
