(E)-3-benzyl-2-<(2,4,5-trimethoxy-3-methylphenyl)-methylene>-7,9,70-trimethoxy-8,11-dimethyl-1,2,3,4,5,6-hexahydro-1,5-imino-3-benzazocine

Base Information

Chemical Name:(E)-3-benzyl-2-<(2,4,5-trimethoxy-3-methylphenyl)-methylene>-7,9,70-trimethoxy-8,11-dimethyl-1,2,3,4,5,6-hexahydro-1,5-imino-3-benzazocine
CAS No.:113531-73-0
Molecular Formula:C₃₄H₄₀N₂O₇
Molecular Weight:588.701
Hs Code.:

Synonyms:(E)-3-benzyl-2-<(2,4,5-trimethoxy-3-methylphenyl)-methylene>-7,9,70-trimethoxy-8,11-dimethyl-1,2,3,4,5,6-hexahydro-1,5-imino-3-benzazocine

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Chemical Property of (E)-3-benzyl-2-<(2,4,5-trimethoxy-3-methylphenyl)-methylene>-7,9,70-trimethoxy-8,11-dimethyl-1,2,3,4,5,6-hexahydro-1,5-imino-3-benzazocine

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Technology Process of (E)-3-benzyl-2-<(2,4,5-trimethoxy-3-methylphenyl)-methylene>-7,9,70-trimethoxy-8,11-dimethyl-1,2,3,4,5,6-hexahydro-1,5-imino-3-benzazocine

There total 7 articles about (E)-3-benzyl-2-<(2,4,5-trimethoxy-3-methylphenyl)-methylene>-7,9,70-trimethoxy-8,11-dimethyl-1,2,3,4,5,6-hexahydro-1,5-imino-3-benzazocine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 50-00-0,30525-89-4,61233-19-0
formaldehyd

: 113461-95-3
11-Benzyl-3,4,6-trimethoxy-5-methyl-12-[1-(2,4,5-trimethoxy-3-methyl-phenyl)-meth-(E)-ylidene]-11,13-diaza-tricyclo[7.3.1.0^2,7]trideca-2⁽⁷⁾,3,5-trien-10-one

: 113531-73-0
(E)-3-benzyl-2-<(2,4,5-trimethoxy-3-methylphenyl)-methylene>-7,9,70-trimethoxy-8,11-dimethyl-1,2,3,4,5,6-hexahydro-1,5-imino-3-benzazocine

Guidance literature:: With formic acid; water; at 70 ℃; for 1h;
DOI:10.3987/R-1987-07-1765

Reference yield:

: 113479-98-4
(Z)-4-benzyl-1-<(isopropyloxy)carbonyl>-6-<2,4,5-trimethoxy-3-methylphenyl)methyl>-3-<(2,4,5-trimethoxy-3-methylphenyl)methylene>-2,5-piperazinedione

: 113531-73-0
(E)-3-benzyl-2-<(2,4,5-trimethoxy-3-methylphenyl)-methylene>-7,9,70-trimethoxy-8,11-dimethyl-1,2,3,4,5,6-hexahydro-1,5-imino-3-benzazocine

Guidance literature:: Multi-step reaction with 4 steps

1: 69 percent / lithium tri-tert-butoxyaluminohydride / tetrahydrofuran / 1 h / 0 °C

2: 60 percent / HCOOH / 1 h / 60 °C

3: 100 percent / conc. H₂SO₄, TFA / 24 h / Ambient temperature

4: 96 percent / H₂O, HCOOH / 1 h / 70 °C

With formic acid; lithium tri(t-butoxy)aluminum hydride; sulfuric acid; water; trifluoroacetic acid; In tetrahydrofuran;
DOI:10.3987/R-1987-07-1765

Reference yield:

: 113461-91-9
(E)-3-benzyl-2-<(2,4,5-trimethoxy-3-methylphenyl)-methylene>-7,9,10-trimethoxy-8-methyl-4-oxo-1,2,3,4,5,6-hexahydro-1,5-imino-3-benzazocine-11-carboxylic acid isopropyl ester

: 113531-73-0
(E)-3-benzyl-2-<(2,4,5-trimethoxy-3-methylphenyl)-methylene>-7,9,70-trimethoxy-8,11-dimethyl-1,2,3,4,5,6-hexahydro-1,5-imino-3-benzazocine

Guidance literature:: Multi-step reaction with 2 steps

1: 100 percent / conc. H₂SO₄, TFA / 24 h / Ambient temperature

2: 96 percent / H₂O, HCOOH / 1 h / 70 °C

With formic acid; sulfuric acid; water; trifluoroacetic acid;
DOI:10.3987/R-1987-07-1765