Technology Process of C31H55NO6Si2
There total 6 articles about C31H55NO6Si2 which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
2,6-di-tert-butyl-pyridine;
In
dichloromethane;
at 20 ℃;
for 18h;
DOI:10.1021/ol300182r
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: osmium(VIII) oxide; water; 4-methylmorpholine N-oxide / tetrahydrofuran / 12 h / 20 °C
2.1: sodium periodate / tetrahydrofuran; water / 1 h / 20 °C
3.1: titanium tetrachloride; sparteine / dichloromethane / 0 °C
3.2: 1 h / 0 °C
4.1: 2,6-di-tert-butyl-pyridine / dichloromethane / 18 h / 20 °C
With
sodium periodate; osmium(VIII) oxide; 2,6-di-tert-butyl-pyridine; water; titanium tetrachloride; 4-methylmorpholine N-oxide; sparteine;
In
tetrahydrofuran; dichloromethane; water;
3.1: Evans asymmetric aldol reaction / 3.2: Evans asymmetric aldol reaction;
DOI:10.1021/ol300182r
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: 1H-imidazole / N,N-dimethyl-formamide / 12 h / 20 °C
2.1: osmium(VIII) oxide; water; 4-methylmorpholine N-oxide / tetrahydrofuran / 12 h / 20 °C
3.1: sodium periodate / tetrahydrofuran; water / 1 h / 20 °C
4.1: titanium tetrachloride; sparteine / dichloromethane / 0 °C
4.2: 1 h / 0 °C
5.1: 2,6-di-tert-butyl-pyridine / dichloromethane / 18 h / 20 °C
With
1H-imidazole; sodium periodate; osmium(VIII) oxide; 2,6-di-tert-butyl-pyridine; water; titanium tetrachloride; 4-methylmorpholine N-oxide; sparteine;
In
tetrahydrofuran; dichloromethane; water; N,N-dimethyl-formamide;
4.1: Evans asymmetric aldol reaction / 4.2: Evans asymmetric aldol reaction;
DOI:10.1021/ol300182r
