Methyl (E)-6,10-anhydro-8-O-benzyl-11-O-(tert-butyldiphenylsilyl)-2,3,5,9-tetradeoxy-7-C-methyl-4-O-(trimethylsilyl)-D-glycero-L-altro-undec-2-enonate

Base Information

Chemical Name:Methyl (E)-6,10-anhydro-8-O-benzyl-11-O-(tert-butyldiphenylsilyl)-2,3,5,9-tetradeoxy-7-C-methyl-4-O-(trimethylsilyl)-D-glycero-L-altro-undec-2-enonate
CAS No.:122821-94-7
Molecular Formula:C₃₉H₅₄O₇Si₂
Molecular Weight:691.025
Hs Code.:

Methyl (E)-6,10-anhydro-8-O-benzyl-11-O-(tert-butyldiphenylsilyl)-2,3,5,9-tetradeoxy-7-C-methyl-4-O-(trimethylsilyl)-D-glycero-L-altro-undec-2-enonate

Synonyms:Methyl (E)-6,10-anhydro-8-O-benzyl-11-O-(tert-butyldiphenylsilyl)-2,3,5,9-tetradeoxy-7-C-methyl-4-O-(trimethylsilyl)-D-glycero-L-altro-undec-2-enonate

Suppliers and Price of Methyl (E)-6,10-anhydro-8-O-benzyl-11-O-(tert-butyldiphenylsilyl)-2,3,5,9-tetradeoxy-7-C-methyl-4-O-(trimethylsilyl)-D-glycero-L-altro-undec-2-enonate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Methyl (E)-6,10-anhydro-8-O-benzyl-11-O-(tert-butyldiphenylsilyl)-2,3,5,9-tetradeoxy-7-C-methyl-4-O-(trimethylsilyl)-D-glycero-L-altro-undec-2-enonate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Methyl (E)-6,10-anhydro-8-O-benzyl-11-O-(tert-butyldiphenylsilyl)-2,3,5,9-tetradeoxy-7-C-methyl-4-O-(trimethylsilyl)-D-glycero-L-altro-undec-2-enonate

There total 5 articles about Methyl (E)-6,10-anhydro-8-O-benzyl-11-O-(tert-butyldiphenylsilyl)-2,3,5,9-tetradeoxy-7-C-methyl-4-O-(trimethylsilyl)-D-glycero-L-altro-undec-2-enonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 122821-89-0
[(2R,3S,4S,6S)-4-Benzyloxy-6-(tert-butyl-diphenyl-silanyloxymethyl)-3-hydroxy-3-methyl-tetrahydro-pyran-2-yl]-acetaldehyde

: 122821-94-7
Methyl (E)-6,10-anhydro-8-O-benzyl-11-O-(tert-butyldiphenylsilyl)-2,3,5,9-tetradeoxy-7-C-methyl-4-O-(trimethylsilyl)-D-glycero-L-altro-undec-2-enonate

Guidance literature:: Multi-step reaction with 4 steps

1: tetrahydrofuran / 0.5 h / 0 °C

2: 85 percent / CH₂Cl₂ / 0.17 h / 0 °C

3: 1.) ozone, 2.) dimethylsulfide, triphenylphosphine / 1.) CH₂Cl₂, -78 deg C, 2 h, 2.) 3 h

4: benzene / 6 h / 25 °C

With dimethylsulfide; ozone; triphenylphosphine; In tetrahydrofuran; dichloromethane; benzene;
DOI:10.1021/ja00199a031

Reference yield:

: 122821-92-5
5,9-Anhydro-7-O-benzyl-10-O-(tert-butyldiphenylsilyl)-1,2,4,8-tetradeoxy-6-C-methyl-3-O-(trimethylsilyl)-D-glycero-L-altro-dec-1-enitol

: 122821-94-7
Methyl (E)-6,10-anhydro-8-O-benzyl-11-O-(tert-butyldiphenylsilyl)-2,3,5,9-tetradeoxy-7-C-methyl-4-O-(trimethylsilyl)-D-glycero-L-altro-undec-2-enonate

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) ozone, 2.) dimethylsulfide, triphenylphosphine / 1.) CH₂Cl₂, -78 deg C, 2 h, 2.) 3 h

2: benzene / 6 h / 25 °C

With dimethylsulfide; ozone; triphenylphosphine; In benzene;
DOI:10.1021/ja00199a031

Reference yield:

: 122821-85-6,122920-04-1
2,6-Anhydro-4-O-benzyl-1-O-(tert-butyldiphenylsilyl)-3,7,8,9-teradeoxy-5-C-methyl-D-altro-non-8-enitol

: 122821-94-7
Methyl (E)-6,10-anhydro-8-O-benzyl-11-O-(tert-butyldiphenylsilyl)-2,3,5,9-tetradeoxy-7-C-methyl-4-O-(trimethylsilyl)-D-glycero-L-altro-undec-2-enonate

Guidance literature:: Multi-step reaction with 5 steps

1: 1.) ozone, 2.) dimethylsulfide, triphenylphosphine / 1.) CH₂Cl₂, -78 deg C, 2 h, 2.) 3 h

2: tetrahydrofuran / 0.5 h / 0 °C

3: 85 percent / CH₂Cl₂ / 0.17 h / 0 °C

4: 1.) ozone, 2.) dimethylsulfide, triphenylphosphine / 1.) CH₂Cl₂, -78 deg C, 2 h, 2.) 3 h

5: benzene / 6 h / 25 °C

With dimethylsulfide; ozone; triphenylphosphine; In tetrahydrofuran; dichloromethane; benzene;
DOI:10.1021/ja00199a031