Dicyclopropa(cd,gh)pentalene, octahydro-1-methylene-

Base Information

Chemical Name:Dicyclopropa(cd,gh)pentalene, octahydro-1-methylene-
CAS No.:3721-64-0
Molecular Formula:C9H10
Molecular Weight:118.1757
Hs Code.:
DSSTox Substance ID:DTXSID30958388

Synonyms:3721-64-0;Dicyclopropa(cd,gh)pentalene, octahydro-1-methylene-;Dicyclopropa[cd,gh]pentalene,octahydro-1-methylene-;DTXSID30958388;1-Methylideneoctahydrodicyclopropa[cd,gh]pentalene

Suppliers and Price of Dicyclopropa(cd,gh)pentalene, octahydro-1-methylene-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 0 raw suppliers

Chemical Property of Dicyclopropa(cd,gh)pentalene, octahydro-1-methylene-

Chemical Property:

Vapor Pressure:4.34mmHg at 25°C
Boiling Point:153.1°Cat760mmHg
Flash Point:31°C
Density:1.17g/cm³
XLogP3:1.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:0
Exact Mass:118.078250319
Heavy Atom Count:9
Complexity:206

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C=C1C2C3C2C4C1C4C3

Technology Process of Dicyclopropa(cd,gh)pentalene, octahydro-1-methylene-

There total 10 articles about Dicyclopropa(cd,gh)pentalene, octahydro-1-methylene- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 78638-81-0,107912-71-0
endo-3-methylidenetricyclo<3.2.1.0^2,4>oct-6-ene

: 3721-64-0
3-Methylidentetracyclo<3.2.1.0^2,4.0^4,6>octan

Guidance literature:: at 140 ℃; for 4h;
DOI:10.1002/hlca.19880710819

Reference yield:

: 51788-41-1,28282-67-9
3-bromo-2,6-bicyclo<3.2.1>octatriene

: 3721-64-0
3-Methylidentetracyclo<3.2.1.0^2,4.0^4,6>octan

Guidance literature:: Multi-step reaction with 4 steps

1: Br₂ / diethyl ether; CCl₄

2: aq. H₂SO₄ / ethanol

3: KOtBu

4: NaH / dimethylsulfoxide

With sulfuric acid; potassium tert-butylate; bromine; sodium hydride; In tetrachloromethane; diethyl ether; ethanol; dimethyl sulfoxide;
DOI:10.1021/ja00947a014

Reference yield:

: anti-8-Brom-tricyclo<3.2.1.0^2,7>octanon-3

: 3721-64-0
3-Methylidentetracyclo<3.2.1.0^2,4.0^4,6>octan

Guidance literature:: Multi-step reaction with 2 steps

1: KOtBu

2: NaH / dimethylsulfoxide

With potassium tert-butylate; sodium hydride; In dimethyl sulfoxide;
DOI:10.1021/ja00947a014