4'-{p-(1,4,8,11-tetraazacyclotetradec-1-ylmethyl)phenyl}-2,2':6',2'-terpyridine

Base Information

Chemical Name:4'-{p-(1,4,8,11-tetraazacyclotetradec-1-ylmethyl)phenyl}-2,2':6',2'-terpyridine
CAS No.:265987-10-8
Molecular Formula:C₃₂H₃₉N₇
Molecular Weight:521.709
Hs Code.:

Synonyms:4'-{p-(1,4,8,11-tetraazacyclotetradec-1-ylmethyl)phenyl}-2,2':6',2'-terpyridine

Suppliers and Price of 4'-{p-(1,4,8,11-tetraazacyclotetradec-1-ylmethyl)phenyl}-2,2':6',2'-terpyridine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 4'-{p-(1,4,8,11-tetraazacyclotetradec-1-ylmethyl)phenyl}-2,2':6',2'-terpyridine

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 4'-{p-(1,4,8,11-tetraazacyclotetradec-1-ylmethyl)phenyl}-2,2':6',2'-terpyridine

There total 1 articles about 4'-{p-(1,4,8,11-tetraazacyclotetradec-1-ylmethyl)phenyl}-2,2':6',2'-terpyridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

: 295-37-4
1,4,8,11-Tetraazacyclotetradecane

: 89972-78-1
4'-(4-bromomethylphenyl)-2,2':6',2''-terpyridine

: 265987-10-8
4'-{p-(1,4,8,11-tetraazacyclotetradec-1-ylmethyl)phenyl}-2,2':6',2'-terpyridine

Guidance literature:: With potassium carbonate; In toluene; at 30 - 100 ℃; Inert atmosphere;
DOI:10.1071/CH09478

Reference yield: 20.0%

: ammonium hexafluorophosphate

: 265987-13-1
[Ru(4'-methyl-2,2':6'2''-terpyridine)Cl₃]

: 265987-10-8
4'-{p-(1,4,8,11-tetraazacyclotetradec-1-ylmethyl)phenyl}-2,2':6',2'-terpyridine

: Ru(C₅H₄N)2C₅H₂NCH₃(CH₂)11N₄H₃C₆H₄C₅H₂N(C₅H₄N)2⁽²⁺⁾*2PF₆^(1-)*2CH₂Cl₂=Ru(C₅H₄N)4C₅H₂NCH₃(CH₂)11N₄H₃C₆H₄C₅H₂N(PF₆)2*2CH₂Cl₂

Guidance literature:: With N-ethylmorpholine;; In methanol; mixt. of ligand with Ru-complex and N-ethylmorpholine in MeOH was heatedat reflux with stirring for 1 h, soln. filtered through Celite, NH4PF6 in MeOH was added to the filtrate; chromy. (silica gel, MeCN/water/aq. KNO3); elem. anal.;
DOI:10.1002/(sici)1099-0682(200004)2000:4<741::aid-ejic741>3.0.co;2-6

Reference yield:

: 22541-53-3,65860-59-5
cobalt(II)

: 265987-10-8
4'-{p-(1,4,8,11-tetraazacyclotetradec-1-ylmethyl)phenyl}-2,2':6',2'-terpyridine

: 349531-90-4
[Co(1-[p-(2,2':6',2''-terpyrid-4'-yl)tolyl]-1,4,8,11-tetraazacyclotetradecane)2]⁽²⁺⁾

Guidance literature:: In water; acetonitrile; soln. Co(2+) and 1-[p-(2,2':6',2''-terpyrid-4'-yl)tolyl]-1,4,8,11-tetraazacyclotetradecane (CH3CN/H2O 70:30, v/v) molar ratio 2:1; acidified; not isolated; detected by differential pulse voltammetry, UV;
DOI:10.1002/1099-0682(200105)2001:5<1227::AID-EJIC1227>3.0.CO;2-0