(1S,2S)-2-(4-bromobenzyl)-1-(tert-butyldimethylsilyloxy)cyclopent-3-ene

Base Information

Chemical Name:(1S,2S)-2-(4-bromobenzyl)-1-(tert-butyldimethylsilyloxy)cyclopent-3-ene
CAS No.:1126011-06-0
Molecular Formula:C₁₈H₂₇BrOSi
Molecular Weight:367.401
Hs Code.:

Synonyms:(1S,2S)-2-(4-bromobenzyl)-1-(tert-butyldimethylsilyloxy)cyclopent-3-ene

Suppliers and Price of (1S,2S)-2-(4-bromobenzyl)-1-(tert-butyldimethylsilyloxy)cyclopent-3-ene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1S,2S)-2-(4-bromobenzyl)-1-(tert-butyldimethylsilyloxy)cyclopent-3-ene

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Technology Process of (1S,2S)-2-(4-bromobenzyl)-1-(tert-butyldimethylsilyloxy)cyclopent-3-ene

There total 2 articles about (1S,2S)-2-(4-bromobenzyl)-1-(tert-butyldimethylsilyloxy)cyclopent-3-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 1126011-13-9
C₁₂H₁₃BrO

: 18162-48-6
tert-butyldimethylsilyl chloride

: 1126011-06-0
(1S,2S)-2-(4-bromobenzyl)-1-(tert-butyldimethylsilyloxy)cyclopent-3-ene

Guidance literature:: With 1H-imidazole; In dichloromethane; at 20 ℃; for 1.5h;
DOI:10.1021/ol802949c

Reference yield:

: 1126011-05-9
(1R,4S)-4-(tert-butyldimethylsilyloxy)cyclopent-2-enyl picolinate

: 589-15-1
1-bromomethyl-4-bromobenzene

: 1126011-06-0
(1S,2S)-2-(4-bromobenzyl)-1-(tert-butyldimethylsilyloxy)cyclopent-3-ene

: 19829-56-2
4,4'-dibromobibenzyl

Guidance literature:: 1-bromomethyl-4-bromobenzene; With magnesium; In diethyl ether; at 0 ℃; for 2h;

With copper(I) bromide dimethylsulfide complex; zinc dibromide; In tetrahydrofuran; diethyl ether; at 0 ℃; for 0.5h; Inert atmosphere;

(1R,4S)-4-(tert-butyldimethylsilyloxy)cyclopent-2-enyl picolinate; In tetrahydrofuran; diethyl ether; at 0 ℃; for 1h; regioselective reaction; Inert atmosphere;
DOI:10.1021/ol802949c

Reference yield: 95.0%

: 1126011-06-0
(1S,2S)-2-(4-bromobenzyl)-1-(tert-butyldimethylsilyloxy)cyclopent-3-ene

: 1126011-09-3
(1S,2R)-2-(4-bromobenzyl)-1-(tert-butyldimethylsilyloxy)cyclopentane

Guidance literature:: With 2-nitrobenzenesulfonyl hydrazide; triethylamine; In tetrahydrofuran; isopropyl alcohol; at 20 ℃;
DOI:10.1021/ol802949c