Technology Process of IrH2(Si(CH3)2C6H5)(C8H12)(P(C6H5)3)
There total 2 articles about IrH2(Si(CH3)2C6H5)(C8H12)(P(C6H5)3) which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
P(C6H5)3;
In
acetone;
byproducts: CH3OSi(CH3)2(C6H5); N2 atmosphere; Ir complex was added to a soln. of PPh3 in acetone and allowed to react at room temp. for 0.5 h; addn. of HSi(CH3)C6H5; mixt. was stirred for 1 h;; concn. under reduced pressure; pptn. by addn. of CH3OH; the ppt. was filtered off, washed with CH3OH, and dried under vac.; elem. anal.;;
- Guidance literature:
-
In
chloroform-d1;
byproducts: HSi(C2H5)3; N2 atmosphere; complex was dissolved in CDCl3 and a 2-fold excess of a silane was added;; not isolated, detected by 1H-NMR-spectroscopy;;
- Guidance literature:
-
With
P(C6H5)3;
In
chloroform-d1;
byproducts: HSi(CH3)2C6H5; N2 atmosphere; molar ratio of complex:phosphine = 1:2, at room temp.;; not isolated, detected by 1H-NMR-spectroscopy;;
