Chemical Property of Bis(1,5-cyclooctadiene)di-mu-methoxydiiridium(I)
Chemical Property:
- Melting Point:154-177 °C
- Boiling Point:°Cat760mmHg
- Flash Point:°C
- PSA：34.14000
- Density:g/cm3
- LogP:5.53980
- Storage Temp.:Room temperature.
- Sensitive.:Light, Air & Moisture Sensitive
- Hydrogen Bond Donor Count:0
- Hydrogen Bond Acceptor Count:2
- Rotatable Bond Count:0
- Exact Mass:662.14810
- Heavy Atom Count:22
- Complexity:74.6
- Purity/Quality:
-
99% *data from raw suppliers
Bis(cyclooctadiene(methoxy)iridium) *data from reagent suppliers
Safty Information:
- Pictogram(s):
- Hazard Codes:Xi
- Statements:
36/37/38
- Safety Statements:
26
- MSDS Files:
-
SDS file from LookChem
Useful:
- Canonical SMILES:C[O-].C[O-].C1CC=CCCC=C1.C1CC=CCCC=C1.[Ir].[Ir]
- Isomeric SMILES:C[O-].C[O-].C1/C=C\CC/C=C\C1.C1/C=C\CC/C=C\C1.[Ir].[Ir]
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Description
DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I), also known as methoxy(cyclooctadiene)iridium(I) dimer, is used as a catalyst in the preparation of heteroaryl fused indole ring systems as inhibition of HCV NS5B polymerase and borylation and Suzuki-miyaura coupling. Further, it is used in tetraborylation reactions, ortho-silylation of aryl ketone, benzaldehyde and benzyl alcohol derivatives through C-H activation. The most useful application is highly regio and enantio selection asymmetric hydroboration. It is a powerful C-H activation catalyst to prepare phenols from arenes. It is also the catalyst of ortho-silylation of aryl ketone, benzaldehyde, and benzyl alcohol derivatives via C-H activation.
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Uses
Methoxy(cyclooctadiene)iridium(I) dimer is used as a catalyst in the preparation of heteroaryl fused indole ring systems and borylation and Suzuki-miyaura coupling. Further, it is used in tetraborylation reactions, ortho-silylation of aryl ketone, benzaldehyde and benzyl alcohol derivatives through C-H activation. The most useful application is highly regio and enantio selection asymmetric hydroboration.
