{Rh3(CNCH3)6(μ-(Ph2PCH2)2PPh)2}(PF6)3*1.3CH2Cl2

Base Information

Chemical Name:{Rh3(CNCH3)6(μ-(Ph2PCH2)2PPh)2}(PF6)3*1.3CH2Cl2
CAS No.:115649-39-3
Molecular Formula:CH₂Cl₂*C₇₆H₇₆N₆P₆Rh₃*3F₆P
Molecular Weight:2113.34
Hs Code.:

Synonyms:{Rh3(CNCH3)6(μ-(Ph2PCH2)2PPh)2}(PF6)3*1.3CH2Cl2

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of {Rh3(CNCH3)6(μ-(Ph2PCH2)2PPh)2}(PF6)3*1.3CH2Cl2

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Technology Process of {Rh3(CNCH3)6(μ-(Ph2PCH2)2PPh)2}(PF6)3*1.3CH2Cl2

There total 1 articles about {Rh3(CNCH3)6(μ-(Ph2PCH2)2PPh)2}(PF6)3*1.3CH2Cl2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

: ammonium hexafluorophosphate

: 84774-75-4
{Rh3(CO)3(μ-Cl)Cl(μ-(Ph2PCH2)2PPh)2}(BPh4)

: 593-75-9,685498-28-6
methyl isocyanate

: 115649-39-3
{Rh3(CNCH3)6(μ-(Ph2PCH2)2PPh)2}(PF6)3*1.3CH2Cl2

Guidance literature:: In methanol; react. in dioxygen-free solvent under N2; reducing of volume by vac. evapn., filtering, washing with MeOH and Et2O, dissolving in CH2CL2, filtering, reprecipitating by addn. of NH4PF6 in MeOH, reducing of some solvent by vac. evapn., filtering, washing with MeOH and Et2O, elem. anal.;
DOI:10.1021/ja00228a021

Reference yield: 94.0%

: 115649-39-3
{Rh3(CNCH3)6(μ-(Ph2PCH2)2PPh)2}(PF6)3*1.3CH2Cl2

: 115590-24-4
{Rh3(CNCH3)6(μ-(Ph2PCH2)2PPh)2I2}(PF6)3

Guidance literature:: With I₂; In acetone; react. under N2; crystn. from Et2O, filtering, washing with Et2O, recrystn. from acetone/Et2O, elem. anal.;
DOI:10.1021/ja00228a021

Reference yield: 93.0%

: 115649-39-3
{Rh3(CNCH3)6(μ-(Ph2PCH2)2PPh)2}(PF6)3*1.3CH2Cl2

: 507-25-5
carbon tetraiodide

: 115590-24-4
{Rh3(CNCH3)6(μ-(Ph2PCH2)2PPh)2I2}(PF6)3

Guidance literature:: In acetone; react. under N2; crystn. from Et2O, filtering, washing with Et2O, recrystn. from acetone/Et2O, elem. anal.;
DOI:10.1021/ja00228a021