(1S,3R)-ethyl 2-benzyl-6-methoxy-1-(3-methoxy-3-oxopropyl)-9-methyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,3,4,9-tetrahydro-1H-pyrido[3,4-b]indole-3-carboxylate

Base Information

Chemical Name:(1S,3R)-ethyl 2-benzyl-6-methoxy-1-(3-methoxy-3-oxopropyl)-9-methyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,3,4,9-tetrahydro-1H-pyrido[3,4-b]indole-3-carboxylate
CAS No.:1443744-19-1
Molecular Formula:C₃₃H₄₃BN₂O₇
Molecular Weight:590.525
Hs Code.:

(1S,3R)-ethyl 2-benzyl-6-methoxy-1-(3-methoxy-3-oxopropyl)-9-methyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,3,4,9-tetrahydro-1H-pyrido[3,4-b]indole-3-carboxylate

Synonyms:(1S,3R)-ethyl 2-benzyl-6-methoxy-1-(3-methoxy-3-oxopropyl)-9-methyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,3,4,9-tetrahydro-1H-pyrido[3,4-b]indole-3-carboxylate

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Chemical Property of (1S,3R)-ethyl 2-benzyl-6-methoxy-1-(3-methoxy-3-oxopropyl)-9-methyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,3,4,9-tetrahydro-1H-pyrido[3,4-b]indole-3-carboxylate

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Technology Process of (1S,3R)-ethyl 2-benzyl-6-methoxy-1-(3-methoxy-3-oxopropyl)-9-methyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,3,4,9-tetrahydro-1H-pyrido[3,4-b]indole-3-carboxylate

There total 1 articles about (1S,3R)-ethyl 2-benzyl-6-methoxy-1-(3-methoxy-3-oxopropyl)-9-methyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,3,4,9-tetrahydro-1H-pyrido[3,4-b]indole-3-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

: 1443744-15-7
(1S,3R)-ethyl 2-benzyl-5-iodo-6-methoxy-1-(3-methoxy-3-oxopropyl)-9-methyl-2,3,4,9-tetrahydro-1H-pyrido[3,4-b]-indole-3-carboxylate

: 73183-34-3
bis(pinacol)diborane

: 1443744-19-1
(1S,3R)-ethyl 2-benzyl-6-methoxy-1-(3-methoxy-3-oxopropyl)-9-methyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,3,4,9-tetrahydro-1H-pyrido[3,4-b]indole-3-carboxylate

: 409095-10-9
trans-N_b-benzyl-3-(ethoxycarbonyl)-6-methoxy-9-methyltetrahydro-β-carboline-1-propionic acid methyl ester

Guidance literature:: With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate; In dimethyl sulfoxide; at 100 ℃; for 10h; Inert atmosphere; Sealed tube;
DOI:10.1021/jo400469t

Reference yield: 38.0%

: 1443744-19-1
(1S,3R)-ethyl 2-benzyl-6-methoxy-1-(3-methoxy-3-oxopropyl)-9-methyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,3,4,9-tetrahydro-1H-pyrido[3,4-b]indole-3-carboxylate

: 1443744-15-7
(1S,3R)-ethyl 2-benzyl-5-iodo-6-methoxy-1-(3-methoxy-3-oxopropyl)-9-methyl-2,3,4,9-tetrahydro-1H-pyrido[3,4-b]-indole-3-carboxylate

: (1R,1′R,3S,3′S)-diethyl 2,2′-dibenzyl-6,6′-dimethoxy-1,1′-bis(3-methoxy-3-oxopropyl)-9,9′-dimethyl-2,2′,3,3′,4,4′,9,9′-octahydro-1H,1′H-[5,5′-bipyrido[3,4-b]indole]-3,3′-dicarboxylate

: (1S,1'S,3R,3'R)-diethyl 2,2'-dibenzyl-6,6'-dimethoxy-1,1'-bis(3-methoxy-3-oxopropyl)-9,9'-dimethyl-2,2',3,3',4,4',9,9'-octahydro-1H,1'H-[5,5'-bipyrido[3,4-b]indole]-3,3'-dicarboxylate

: 409095-10-9
trans-N_b-benzyl-3-(ethoxycarbonyl)-6-methoxy-9-methyltetrahydro-β-carboline-1-propionic acid methyl ester

Guidance literature:: With potassium phosphate; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; 2-dicyclohexylphosphino-2′,6′-dimethoxybiphenyl; In tetrahydrofuran; water; at 50 ℃; for 48h; Reagent/catalyst; Time; Inert atmosphere; Sealed tube;
DOI:10.1021/jo400469t

Reference yield:

: 1443744-19-1
(1S,3R)-ethyl 2-benzyl-6-methoxy-1-(3-methoxy-3-oxopropyl)-9-methyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,3,4,9-tetrahydro-1H-pyrido[3,4-b]indole-3-carboxylate

: 1443744-17-9
(1S,3R)-ethyl 2-benzyl-5-bromo-6-methoxy-1-(3-methoxy-3-oxopropyl)-9-methyl-2,3,4,9-tetrahydro-1H-pyrido[3,4-b]-indole-3-carboxylate

: 409095-10-9
trans-N_b-benzyl-3-(ethoxycarbonyl)-6-methoxy-9-methyltetrahydro-β-carboline-1-propionic acid methyl ester

Guidance literature:: With potassium phosphate; palladium diacetate; CyJohnPhos; In 1,4-dioxane; water; at 100 ℃; for 24h; Inert atmosphere; Sealed tube;
DOI:10.1021/jo400469t