6,11-Hexadecadien-1-ol, acetate, (E,Z)-

Base Information

• Chemical Name: 6,11-Hexadecadien-1-ol, acetate, (E,Z)-
• CAS No.: 83483-57-2
• Molecular Formula: C₁₈H₃₂O₂
• Molecular Weight: 280.451
• Wikidata: Q76386765
• Metabolomics Workbench ID: 4003
• Mol file: 83483-57-2.mol

Synonyms:6,11-Hexadecadien-1-ol, acetate, (E,Z)-;6E,11Z-Hexadecadienyl acetate;83483-57-2;[(6E,11Z)-hexadeca-6,11-dienyl] acetate;SCHEMBL1301531;(e,z)-6,11-hexadecadienyl acetate;LMFA07010358;FA(18:2)

Chemical Property of 6,11-Hexadecadien-1-ol, acetate, (E,Z)-

Chemical Property:

• Vapor Pressure: 1.49E-05mmHg at 25°C
• Boiling Point: 366.2°Cat760mmHg
• Flash Point: 102.4°C
• PSA: 26.30000
• Density: 0.886g/cm³
• LogP: 5.58280
• XLogP3: 6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 14
• Exact Mass: 280.240230259
• Heavy Atom Count: 20
• Complexity: 267

Purity/Quality:

85.0-99.8% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCC=CCCCC=CCCCCCOC(=O)C
• Isomeric SMILES: CCCC/C=C\CCC/C=C/CCCCCOC(=O)C

Technology Process of 6,11-Hexadecadien-1-ol, acetate, (E,Z)-

There total 16 articles about 6,11-Hexadecadien-1-ol, acetate, (E,Z)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

(6Z,11E)-6,11-Hexadecadien-1-ol (83483-56-1) + acetyl chloride (75-36-5) → (6Z,11E)-6,11-Hexadecadienylacetat (83483-57-2)

Guidance literature:

With pyridine; In tetrahydrofuran; 1) -20 deg C, 0.5 h, 2) r.t., 3 h;

DOI:10.1055/s-1990-27089

Reference yield: 58.0%

(6Z,11E)-6,11-Hexadecadien-1-ol (83483-56-1) + acetic anhydride (108-24-7) → (6Z,11E)-6,11-Hexadecadienylacetat (83483-57-2)

Guidance literature:

With pyridine;

DOI:10.1002/jlac.198219820807

Reference yield:

1-(trimethylsilyl)-1-hexyne (3844-94-8) → (6Z,11E)-6,11-Hexadecadienylacetat (83483-57-2)

Guidance literature:

Multi-step reaction with 6 steps

1: 1) DIBAH, 2) I₂ / 1) Et₂O, hexane, a) r.t., 0.5 h, b) 40 deg C, 1 h, 2) Et₂O, -78 deg C, 1 h

2: NaOMe / methanol / 4 h / 40 °C

4: 78 percent / acetonitrile / 24 h / Heating

6: 80 percent / Py / tetrahydrofuran / 1) -20 deg C, 0.5 h, 2) r.t., 3 h

With pyridine; iodine; sodium methylate; diisobutylaluminium hydride; In tetrahydrofuran; methanol; acetonitrile;

DOI:10.1055/s-1990-27089

upstream raw materials:

(6Z,11E)-6,11-Hexadecadien-1-ol

acetic anhydride

acetyl chloride

11-(2-tetrahydropyranyloxy)-5Z-undecenal