Methyl perfluoroisobutyl ether

Base Information

• Chemical Name: Methyl perfluoroisobutyl ether
• CAS No.: 163702-08-7
• Molecular Formula: C5H3 F9 O
• Molecular Weight: 250.064
• European Community (EC) Number: 605-340-9
• UNII: HI89P35AAX
• DSSTox Substance ID: DTXSID5042326
• Nikkaji Number: J1.292.804A
• Wikidata: Q27279946
• RXCUI: 1431149
• ChEMBL ID: CHEMBL477673
• Mol file: 163702-08-7.mol

Synonyms:Methyl perfluoroisobutyl ether;163702-08-7;perfluoroisobutyl methyl ether;Propane, 2-(difluoromethoxymethyl)-1,1,1,2,3,3,3-heptafluoro-;HI89P35AAX;2-[difluoro(methoxy)methyl]-1,1,1,2,3,3,3-heptafluoropropane;UNII-HI89P35AAX;(CF3)2CFCF2OCH3;Methylnonafluoroisobutyl ether;SCHEMBL366639;methyl perfluoroisobutanyl ether;CHEMBL477673;DTXSID5042326;AKOS040767511;METHYL PERFLUOROISOBUTYL ETHER [INCI];Q27279946;1,1,1,2,3,3-hexafluoro-3-methoxy-2-(trifluoromethyl)propane;2-[Difluoro(methoxy)methyl]-1,1,1,2,3,3,3-heptafluoro-propane;1,1,2,3,3,3-HEXAFLUORO-1-METHOXY-2-(TRIFLUOROMETHYL)PROPANE

Chemical Property of Methyl perfluoroisobutyl ether

Chemical Property:

• Vapor Pressure: 909mmHg at 25°C
• Boiling Point: 20.0±40.0℃ (760 Torr)
• Flash Point: -29.6±23.2℃
• PSA: 9.23000
• Density: 1.500±0.06 g/cm3 (20 ºC 760 Torr)
• LogP: 3.05850
• XLogP3: 3.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 10
• Rotatable Bond Count: 2
• Exact Mass: 250.00401817
• Heavy Atom Count: 15
• Complexity: 212

Purity/Quality:

99%, ^*data from raw suppliers

2-(DIFLUOROMETHOXYMETHYL)-1,1,1,2,3,3,3-HEPTAFLUOROPROPANE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Other Classes -> Halogenated Ethers
• Canonical SMILES: COC(C(C(F)(F)F)(C(F)(F)F)F)(F)F
• Uses: Methyl perfluoroisobutyl ether is a useful research chemical.

Technology Process of Methyl perfluoroisobutyl ether

There total 5 articles about Methyl perfluoroisobutyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.2%

Dimethyl ether (115-10-6,157621-61-9) + perfluoroisobutyryl fluoride (677-84-9) → nonafluoroisobutyl methyl ether (163702-08-7)

Guidance literature:

perfluoroisobutyryl fluoride; With silver fluoride; at 20 ℃; for 24h; Autoclave;

Dimethyl ether; With water; at 20 ℃; for 48h; Autoclave;

Reference yield: 83.0%

1-chloro-1-methoxy-2-trifluoromethyl-3,3,3-trifluoro-1-propene → nonafluoroisobutyl methyl ether (163702-08-7)

Guidance literature:

With zinc-chromium-iron; hydrogen fluoride; chlorine; at 300 ℃; Temperature;

Reference yield: 71.0%

→ nonafluoroisobutyl methyl ether (163702-08-7)

Guidance literature:

upstream raw materials:

1,3,3,3-tetrafluoro-1-methoxy-2-trifluoromethyl-propene

methyl fluoroformate

perfluoroisobutyryl fluoride

Dimethyl ether

Downstream raw materials:

Carbonyl fluoride

Refernces

• 1、 -. "Method for synthesizing perfluorobutyl methyl ether". Paragraph 0025; 0039-0041; 0055-0056. . Retrieved 2020/12/10.
• 2、 -. "Process for preparing hydrofluoroethers". Page 7. . Retrieved 2008/06/13.