Technology Process of C11H11Br2NO3S
There total 1 articles about C11H11Br2NO3S which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
3,5-dibromobenzoic acid;
With
O-(benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium tetrafluoroborate;
In
N,N-dimethyl-formamide;
at 22 ℃;
for 0.0833333h;
Inert atmosphere;
thiomorpholine 1,1-dioxide;
With
N-ethyl-N,N-diisopropylamine;
at 22 ℃;
for 24h;
- Guidance literature:
-
With
potassium carbonate;
copper(l) iodide; L-proline;
In
dimethyl sulfoxide;
at 85 ℃;
for 20h;
Inert atmosphere;
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: potassium carbonate / L-proline; copper(l) iodide / dimethyl sulfoxide / 20 h / 85 °C / Inert atmosphere
2.1: triethylamine / tetrakis(triphenylphosphine) palladium(0); copper(l) iodide / dimethyl sulfoxide; tetrahydrofuran / 3 h / 45 - 50 °C / Inert atmosphere; Sealed vessel
2.2: 0.5 h / 45 °C / Inert atmosphere
3.1: triethylamine / tetrakis(triphenylphosphine) palladium(0); copper(l) iodide / N,N-dimethyl-formamide / 14.25 h / 22 - 85 °C / Inert atmosphere; Sealed vessel
3.2: 3 h / 90 °C / Sealed vessel
4.1: dichloromethane / 0.67 h / 22 °C
5.1: hydrogenchloride / ethanol
With
hydrogenchloride; potassium carbonate; triethylamine;
copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); L-proline;
In
tetrahydrofuran; ethanol; dichloromethane; dimethyl sulfoxide; N,N-dimethyl-formamide;
